{"title":"世界河流水系中有机生态毒物弥散相分布模式","authors":"M. V. Milyukin, М.V. Gorban","doi":"10.17721/moca.2022.133-140","DOIUrl":null,"url":null,"abstract":"The results of the dispersed-phase distribution of major classes of organic ecotoxicants such as organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) in the water of various river systems have been discussed in the current research. The main parameters of water quality in these river systems differ significantly. Despite this, the following constancy has been established for all studied river systems: the higher the hydrophobicity coefficient log (Ko/w) of the organic ecotoxicant, the smaller its water-soluble fraction. Relevant dependences have been established and their statistical processing has been carried out. The correlations determined are significant and reliable for most aquatic systems, with R ranging from 0.67 to 0.98 (P > 95%). It follows that the hydrophobicity coefficient of a compound is an essential parameter by which its disperse-phase distribution can be estimated. The results were almost identical for the Dnieper and Elbe rivers due to the similar physicochemical characteristics of these water systems.","PeriodicalId":18626,"journal":{"name":"Methods and Objects of Chemical Analysis","volume":null,"pages":null},"PeriodicalIF":0.7000,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Patterns of the Disperse-phase Distribution of Organic Ecotoxicants in the Water of the World River Systems\",\"authors\":\"M. V. Milyukin, М.V. Gorban\",\"doi\":\"10.17721/moca.2022.133-140\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The results of the dispersed-phase distribution of major classes of organic ecotoxicants such as organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) in the water of various river systems have been discussed in the current research. The main parameters of water quality in these river systems differ significantly. Despite this, the following constancy has been established for all studied river systems: the higher the hydrophobicity coefficient log (Ko/w) of the organic ecotoxicant, the smaller its water-soluble fraction. Relevant dependences have been established and their statistical processing has been carried out. The correlations determined are significant and reliable for most aquatic systems, with R ranging from 0.67 to 0.98 (P > 95%). It follows that the hydrophobicity coefficient of a compound is an essential parameter by which its disperse-phase distribution can be estimated. The results were almost identical for the Dnieper and Elbe rivers due to the similar physicochemical characteristics of these water systems.\",\"PeriodicalId\":18626,\"journal\":{\"name\":\"Methods and Objects of Chemical Analysis\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2022-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Methods and Objects of Chemical Analysis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.17721/moca.2022.133-140\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Methods and Objects of Chemical Analysis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.17721/moca.2022.133-140","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Patterns of the Disperse-phase Distribution of Organic Ecotoxicants in the Water of the World River Systems
The results of the dispersed-phase distribution of major classes of organic ecotoxicants such as organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) in the water of various river systems have been discussed in the current research. The main parameters of water quality in these river systems differ significantly. Despite this, the following constancy has been established for all studied river systems: the higher the hydrophobicity coefficient log (Ko/w) of the organic ecotoxicant, the smaller its water-soluble fraction. Relevant dependences have been established and their statistical processing has been carried out. The correlations determined are significant and reliable for most aquatic systems, with R ranging from 0.67 to 0.98 (P > 95%). It follows that the hydrophobicity coefficient of a compound is an essential parameter by which its disperse-phase distribution can be estimated. The results were almost identical for the Dnieper and Elbe rivers due to the similar physicochemical characteristics of these water systems.
期刊介绍:
The journal "Methods and objects of chemical analysis" is peer-review journal and publishes original articles of theoretical and experimental analysis on topical issues and bio-analytical chemistry, chemical and pharmaceutical analysis, as well as chemical metrology. Submitted works shall cover the results of completed studies and shall make scientific contributions to the relevant area of expertise. The journal publishes review articles, research articles and articles related to latest developments of analytical instrumentations.