{"title":"磺胺硝基DAF试剂间接测定水中磷酸盐离子","authors":"S. Kel’ina, O. G. Nevinsky","doi":"10.17721/moca.2021.147-152","DOIUrl":null,"url":null,"abstract":"An indirect method for the determination of phosphate ions in natural and treated wastewater is proposed, which is based on the formation of molybdophosphate complex (MFC), separating it from excess unbound molybdate by isoamyl acetate extraction, extraction of MFC into weakly alkaline aqueous phase, destruction of MFC and photometric determination of the equivalent amount of molybdate ions with the sulfonitrazo DAF reagent. The technique allows to determine from 0.02 to 0.43 mg dm-3 of phosphate ion (in terms of phosphorus).","PeriodicalId":18626,"journal":{"name":"Methods and Objects of Chemical Analysis","volume":"151 1","pages":""},"PeriodicalIF":0.7000,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Indirect Determination of Phosphate-ions in Waters with the Reagent Sulfonitrazo DAF\",\"authors\":\"S. Kel’ina, O. G. Nevinsky\",\"doi\":\"10.17721/moca.2021.147-152\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"An indirect method for the determination of phosphate ions in natural and treated wastewater is proposed, which is based on the formation of molybdophosphate complex (MFC), separating it from excess unbound molybdate by isoamyl acetate extraction, extraction of MFC into weakly alkaline aqueous phase, destruction of MFC and photometric determination of the equivalent amount of molybdate ions with the sulfonitrazo DAF reagent. The technique allows to determine from 0.02 to 0.43 mg dm-3 of phosphate ion (in terms of phosphorus).\",\"PeriodicalId\":18626,\"journal\":{\"name\":\"Methods and Objects of Chemical Analysis\",\"volume\":\"151 1\",\"pages\":\"\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2021-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Methods and Objects of Chemical Analysis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.17721/moca.2021.147-152\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Methods and Objects of Chemical Analysis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.17721/moca.2021.147-152","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Indirect Determination of Phosphate-ions in Waters with the Reagent Sulfonitrazo DAF
An indirect method for the determination of phosphate ions in natural and treated wastewater is proposed, which is based on the formation of molybdophosphate complex (MFC), separating it from excess unbound molybdate by isoamyl acetate extraction, extraction of MFC into weakly alkaline aqueous phase, destruction of MFC and photometric determination of the equivalent amount of molybdate ions with the sulfonitrazo DAF reagent. The technique allows to determine from 0.02 to 0.43 mg dm-3 of phosphate ion (in terms of phosphorus).
期刊介绍:
The journal "Methods and objects of chemical analysis" is peer-review journal and publishes original articles of theoretical and experimental analysis on topical issues and bio-analytical chemistry, chemical and pharmaceutical analysis, as well as chemical metrology. Submitted works shall cover the results of completed studies and shall make scientific contributions to the relevant area of expertise. The journal publishes review articles, research articles and articles related to latest developments of analytical instrumentations.