铽铕离子掺杂NaBaY(BO3)2发光材料的制备

IF 0.3 Q4 CHEMISTRY, MULTIDISCIPLINARY

Chemical Bulletin of Kazakh National University Pub Date : 2020-06-05 DOI:10.15328/cb1122

Zh. K. Orazov, A. Bolatov, N. Kononova, V. Shevchenko, K. Kokh, B. Uralbekov, A. Kuznetsov, A. Kokh

{"title":"铽铕离子掺杂NaBaY(BO3)2发光材料的制备","authors":"Zh. K. Orazov, A. Bolatov, N. Kononova, V. Shevchenko, K. Kokh, B. Uralbekov, A. Kuznetsov, A. Kokh","doi":"10.15328/cb1122","DOIUrl":null,"url":null,"abstract":"A new luminescent material based on complex borate NaBaY(BO3)2 doped with Tb3+ and Eu3+ ions was obtained by high-temperature solid-state synthesis. Using X-ray diffraction analysis it was shown that NaBaY(BO3)2:0.07Tb3+:0.1Eu3+ crystallizes in trigonal system with the space group R-3m and isotypic with the mineral buetschliit K2Ca(CO3)2. The crystal structure of the phosphor is layered, formed from [BO3] triangles, [YO6] octahedra, [BaO9] and [NaO9] polyhedra. The calculated unit cell parameters for NaBaY(BO3)2:0.07Tb3+:0.1Eu3+ are: a=5.3510(6) Å, c=17.9338(3) Å, V=444.71(2) Å3. The luminescent properties of NaBaY(BO3)2:0.07Tb3+:0.1Eu3+ were studied.","PeriodicalId":9860,"journal":{"name":"Chemical Bulletin of Kazakh National University","volume":null,"pages":null},"PeriodicalIF":0.3000,"publicationDate":"2020-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Obtaining of luminescent material based on NaBaY(BO3)2 doped with terbium and europium ions\",\"authors\":\"Zh. K. Orazov, A. Bolatov, N. Kononova, V. Shevchenko, K. Kokh, B. Uralbekov, A. Kuznetsov, A. Kokh\",\"doi\":\"10.15328/cb1122\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A new luminescent material based on complex borate NaBaY(BO3)2 doped with Tb3+ and Eu3+ ions was obtained by high-temperature solid-state synthesis. Using X-ray diffraction analysis it was shown that NaBaY(BO3)2:0.07Tb3+:0.1Eu3+ crystallizes in trigonal system with the space group R-3m and isotypic with the mineral buetschliit K2Ca(CO3)2. The crystal structure of the phosphor is layered, formed from [BO3] triangles, [YO6] octahedra, [BaO9] and [NaO9] polyhedra. The calculated unit cell parameters for NaBaY(BO3)2:0.07Tb3+:0.1Eu3+ are: a=5.3510(6) Å, c=17.9338(3) Å, V=444.71(2) Å3. The luminescent properties of NaBaY(BO3)2:0.07Tb3+:0.1Eu3+ were studied.\",\"PeriodicalId\":9860,\"journal\":{\"name\":\"Chemical Bulletin of Kazakh National University\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.3000,\"publicationDate\":\"2020-06-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Bulletin of Kazakh National University\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.15328/cb1122\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Bulletin of Kazakh National University","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.15328/cb1122","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

采用高温固相合成方法，制备了一种以Tb3+和Eu3+离子掺杂的配合硼酸盐NaBaY(BO3)2为基础的新型发光材料。x射线衍射分析表明，NaBaY(BO3)2:0. 7 tb3 +:0.1Eu3+为空间群R-3m的三角晶系，与矿石K2Ca(CO3)2等型。荧光粉的晶体结构呈层状，由[BO3]三角形、[YO6]八面体、[BaO9]和[NaO9]多面体组成。计算得到NaBaY(BO3)2:0.07Tb3+:0.1Eu3+的晶胞参数为:a=5.3510(6) Å， c=17.9338(3) Å， V=444.71(2) Å3。研究了NaBaY(BO3)2:0.07Tb3+:0.1Eu3+的发光性能。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Obtaining of luminescent material based on NaBaY(BO3)2 doped with terbium and europium ions

A new luminescent material based on complex borate NaBaY(BO3)2 doped with Tb3+ and Eu3+ ions was obtained by high-temperature solid-state synthesis. Using X-ray diffraction analysis it was shown that NaBaY(BO3)2:0.07Tb3+:0.1Eu3+ crystallizes in trigonal system with the space group R-3m and isotypic with the mineral buetschliit K2Ca(CO3)2. The crystal structure of the phosphor is layered, formed from [BO3] triangles, [YO6] octahedra, [BaO9] and [NaO9] polyhedra. The calculated unit cell parameters for NaBaY(BO3)2:0.07Tb3+:0.1Eu3+ are: a=5.3510(6) Å, c=17.9338(3) Å, V=444.71(2) Å3. The luminescent properties of NaBaY(BO3)2:0.07Tb3+:0.1Eu3+ were studied.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Chemical Bulletin of Kazakh National University

自引率

0.00%

发文量

审稿时长

10 weeks