氯铝酸盐离子液体中周期性铝丝的电位振荡相关恒流沉积

ECS Electrochemistry Letters Pub Date : 2015-01-01 DOI:10.1149/2.0021507EEL

C. Su, I. Sun

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引用次数: 6

摘要

所有电化学实验均在38◦C的氮气填充手套箱中使用传统的三电极电池，在静止的AlCl3/TMHC (58/42 mol%)中进行。用Al螺旋丝(Alfa Aesar, 99.95%)浸泡在大量IL中作为对电极，参比电极为Al丝，在填充相同IL的熔融玻璃管中，工作电极为W丝(直径=0.5 mm)。电化学实验采用EG&G PARC Model 263A恒电位器/恒电位器，由EG&G Model 270软件控制。采用高分辨率扫描电子显微镜(HITACHI, SU8000)检查沉积物的形貌。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Potential Oscillation Associated Galvanostatic Deposition of Periodic Al Wires from a Chloroaluminate Ionic Liquid

Experimental All the electrochemical experiments were carried out in the quiescent AlCl3/TMHC (58/42 mol%) in a N2-filled glove box at 38 ◦ C using a conventional three-electrode cell. An Al spiral wire (Alfa Aesar, 99.95%) immersed in the bulk IL was used as the counter electrode, the reference electrode was an Al wire in a fritted glass tube filled with the same IL. The working electrode was a W wire (diameter =0.5 mm). The electrochemical experiments were performed with an EG&G PARC Model 263A potentiostat/galvanostat controlled with EG&G Model 270 software. High-resolution scanning electron microscopy (HITACHI, SU8000) was used to examine the morphology of the deposits.

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来源期刊

ECS Electrochemistry Letters ELECTROCHEMISTRY-MATERIALS SCIENCE, MULTIDISCIPLINARY

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