原位聚合法制备锂离子电池介孔Si@PAN电极

ECS Electrochemistry Letters Pub Date : 2015-01-01 DOI:10.1149/2.0011503EEL

Thomas A. Yersak, Jaewook Shin, Ziying Wang, Daniel Estrada, J. Whiteley, Sehee Lee, M. Sailor, Y. Meng

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Preparation of Mesoporous Si@PAN Electrodes for Li-Ion Batteries via the In-Situ Polymerization of PAN

(electrode), the ﬁrst cycle coulombic efﬁciency of these electrodeswas still less than 50% without a pre-lithiation treatment. The results of an all-solid-state battery experiment conﬁrmed that low ﬁrstcycle reversibility should be attributed primarily to mechanical pulverization of the internal porous structure of mp-Si particles.© 2015 The Electrochemical Society. [DOI: 10.1149/2.0011503eel] All rights reserved.Manuscript received December 12, 2014. Published January 9, 2015.

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ECS Electrochemistry Letters ELECTROCHEMISTRY-MATERIALS SCIENCE, MULTIDISCIPLINARY

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