向列液晶中的吸附现象和锚定能

IF 4.8 3区 材料科学 Q2 CHEMISTRY, PHYSICAL
G. Barbero, L. R. Evangelista
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引用次数: 128

摘要

向列相-各向同性相变连续体的向列序参数Maier-Saupe方法强、弱锚固状态下向列相外场对弹性能量密度平衡构型的贡献向列型液晶的自发周期性畸变:依赖于倾斜角度理论模型的表面自由能对锚定能的随机贡献向列型表面锚定能对表面能温度的贡献的向列弹性模型的rapinii - papolar表达式的偏差表面自由能对溶向液晶表面导向滑动的热弛豫模型蒸发SiOx取向的向列型液晶中锚定能温度诱导表面转变的热重整化相变的局部自一致方法在向列型液晶-壁面界面表面吸附颗粒:一般特性介绍问题的陈述:Langmuir等温线表面吸附与锚定过渡光操纵光致变色向列型液晶的锚定强度磁性颗粒在磁流体中吸附在液晶表面的选择性离子吸附电场致向列型液晶样品的不稳定性一般静电模型分析ⅰ:特征值问题的变分解分析ⅱ:本征值问题的级数解弹性项线性在一维几何向列方向空间导数中的作用结论离子与向列表面能:离子源电场的超指数近似非线性泊松-玻尔兹曼方程外电场效应中向列锚定能对介电表面能的贡献来源结论吸附现象和外电场效应对含杂质各向异性液体的介绍模型中电荷和场的分布离子吸附在无外电平衡时电荷分布的扩展模型中吸附能对介电的贡献的影响锚定能类费米吸附现象的描述介绍类费米模型的应用:离子在各向同性流体中的吸附限制数值结果的结论
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Adsorption phenomena and anchoring energy in nematic liquid crystals
NEMATIC LIQUID CRYSTALS: FUNDAMENTALS AND BULK PROPERTIES Nematic Order Parameters Maier-Saupe Approach for the Nematic-Isotropic Phase Transition Continuum Description of the Nematic Phase External Field Contribution to the Elastic Energy Density Equilbrium Configuration in Strong and Weak Anchoring Situations NEMATIC LIQUID CRYSTALS: SURFACE PROPERTIES Anchoring The Anchoring Energy Function Periodic Deformations in Nematic Liquid Crystals Spontaneous Periodic Distortions in Nematic Liquid Crystals: Dependence on the Tilt Angle Theoretical Models for the Surface Free Energy Stochastic Contribution to the Anchoring Energy: Deviation from the Rapini-Papolar Expression Validity of the Elastic Model for Nematic Surface Anchoring Energy Contribution of the Smectic-Nematic to the Surface Energy TEMPERATURE DEPENDENCE OF THE SURFACE FREE ENERGY Thermal Relaxation Model of Surface Director Gliding in Lyotropic Liquid Crystals Thermal Renormalization of the Anchoring Energy Temperature Induced Surface Transition in Nematic Liquid Crystals Oriented by Evaporated SiOx A Local Self-Consistent Approach to the Phase Transition at the Nematic Liquid Crystal - Wall Interface SURFACE ADSORPTION OF PARTICLES: GENERAL CHARACTERISTICS Introduction Statement of the Problem: Langmuir's Isotherm Surface Adsorption and Anchoring Transition Photo-Manipulation of the Anchoring Strength of Photochromic Nematic Liquid Crystal Adsorption of Magnetic Grains in Magnetic Fluids Selective Ionic Adsorption in Liquid Crystals SURFACE ELECTRIC FIELD-INDUCED INSTABILITIES IN NEMATIC LIQUID CRYSTALS SAMPLE The General Electrostatic Model Analysis I: Variation Solution of the Eigenvalue Problem Analysis II: Series Solution of the Eigenvalue Problem Role of the Elastic Term Linear in the Spatial Derivatives of the Nematic Director in a 1D Geometry Conclusions IONS AND NEMATIC SURFACE ENERGY: BEYOND THE EXPONENTIAL APPROXIMATION FOR THE ELECTRIC FIELD OF IONIC ORIGIN Introduction Theoretical Model: Non-Linear Poisson-Boltzman Equation External Electric Field Effect in the Nematic Anchoring Energy Contribution to the Surface Energy of Dielectric Origin Conclusions ADSORPTION PHENOMENON AND EXTERNAL FIELD EFFECT ON AN ISOTROPIC LIQUID CONTAINING IMPURITIES Introduction The Model The Charge and Field Distributions Ionic Adsorption in the Absence of External Equilibrium Distribution of Charges Extensions of the Model Influence of the Adsorption Energy in the Dieletric Contribution to the Anchoring Energy FERMILIKE DESCRIPTION OF THE ADSORPTION PHENOMENON Introduction The Fermi-Like Model Application: Ion Adsorption in Isotropic Fluids Limits Numerical Results Conclusions
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来源期刊
Liquid Crystals Reviews
Liquid Crystals Reviews CHEMISTRY, PHYSICALCRYSTALLOGRAPHY&n-CRYSTALLOGRAPHY
CiteScore
7.60
自引率
5.90%
发文量
8
期刊介绍: Liquid Crystals Reviews publishes review articles on all aspects of liquid crystal fundamentals and applied science, including experimental and theoretical studies of physical and chemical properties, molecular design and synthesis and engineering of liquid crystal devices. The Journal fosters cross-disciplinary exchange of ideas, encouraging authors to present material at a level accessible to specialists from other fields of science and engineering. Liquid Crystals Reviews provides the scientific community, in both academia and industry, with a publication of standing, guaranteed by the Editors and by the International Editorial Board who are active scientists in the worldwide liquid crystal community.
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