Chengsen Li, Xueping Gao, Bo Zhu, Xiaomin Yuan, Zhijie Qiu, Ye Zhang, Shuhan Yan
{"title":"用马来酰亚胺改性水性聚氨酯施胶剂改善碳纤维增强环氧树脂复合材料的界面性能","authors":"Chengsen Li, Xueping Gao, Bo Zhu, Xiaomin Yuan, Zhijie Qiu, Ye Zhang, Shuhan Yan","doi":"10.1002/app.53611","DOIUrl":null,"url":null,"abstract":"<p>The N-(4-hydroxyphenyl) maleimide (4-HPM) modified waterborne polyurethane emulsions (MWPU) were used as surface sizing agents to improve the interfacial adhesion between carbon fibers (CF) and epoxy resin matrix. Dynamic light scattering (DLS), transmission electron microscope (TEM), and thermogravimetric analysis (TGA) showed the particle size distribution, storage stability, and thermal stability of the modified MWPU. And the surface reactivity of CF increased significantly after sizing. The interfacial shear strength (IFSS) and the interlaminar shear strength (ILSS) of CFREs were tested, and the fracture morphology was observed. The result showed that a continuous and uniform sizing layer is formed on the surface of CF. In particular, the comprehensive performance and interfacial modification effect of the MWPU emulsion outperformed other samples when the 4-HPM content was 1.0 wt%. Compared with unsized carbon fibers, the IFSS and ILSS are up to 71.30% and 30.81% higher, respectively.</p>","PeriodicalId":183,"journal":{"name":"Journal of Applied Polymer Science","volume":"140 11","pages":""},"PeriodicalIF":2.7000,"publicationDate":"2023-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"Improve the interfacial properties of carbon fiber reinforced epoxy resin composites by maleimide-modified waterborne polyurethane sizing agent\",\"authors\":\"Chengsen Li, Xueping Gao, Bo Zhu, Xiaomin Yuan, Zhijie Qiu, Ye Zhang, Shuhan Yan\",\"doi\":\"10.1002/app.53611\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The N-(4-hydroxyphenyl) maleimide (4-HPM) modified waterborne polyurethane emulsions (MWPU) were used as surface sizing agents to improve the interfacial adhesion between carbon fibers (CF) and epoxy resin matrix. Dynamic light scattering (DLS), transmission electron microscope (TEM), and thermogravimetric analysis (TGA) showed the particle size distribution, storage stability, and thermal stability of the modified MWPU. And the surface reactivity of CF increased significantly after sizing. The interfacial shear strength (IFSS) and the interlaminar shear strength (ILSS) of CFREs were tested, and the fracture morphology was observed. The result showed that a continuous and uniform sizing layer is formed on the surface of CF. In particular, the comprehensive performance and interfacial modification effect of the MWPU emulsion outperformed other samples when the 4-HPM content was 1.0 wt%. Compared with unsized carbon fibers, the IFSS and ILSS are up to 71.30% and 30.81% higher, respectively.</p>\",\"PeriodicalId\":183,\"journal\":{\"name\":\"Journal of Applied Polymer Science\",\"volume\":\"140 11\",\"pages\":\"\"},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2023-01-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Applied Polymer Science\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/app.53611\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Applied Polymer Science","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/app.53611","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Improve the interfacial properties of carbon fiber reinforced epoxy resin composites by maleimide-modified waterborne polyurethane sizing agent
The N-(4-hydroxyphenyl) maleimide (4-HPM) modified waterborne polyurethane emulsions (MWPU) were used as surface sizing agents to improve the interfacial adhesion between carbon fibers (CF) and epoxy resin matrix. Dynamic light scattering (DLS), transmission electron microscope (TEM), and thermogravimetric analysis (TGA) showed the particle size distribution, storage stability, and thermal stability of the modified MWPU. And the surface reactivity of CF increased significantly after sizing. The interfacial shear strength (IFSS) and the interlaminar shear strength (ILSS) of CFREs were tested, and the fracture morphology was observed. The result showed that a continuous and uniform sizing layer is formed on the surface of CF. In particular, the comprehensive performance and interfacial modification effect of the MWPU emulsion outperformed other samples when the 4-HPM content was 1.0 wt%. Compared with unsized carbon fibers, the IFSS and ILSS are up to 71.30% and 30.81% higher, respectively.
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The Journal of Applied Polymer Science is the largest peer-reviewed publication in polymers, #3 by total citations, and features results with real-world impact on membranes, polysaccharides, and much more.
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