多孔卟啉基金属有机骨架:合成、结构、吸附性能及应用前景

IF 7 2区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Reviews Pub Date : 2022-01-01 DOI:10.1070/RCR5038

Yulia G. Gorbunova, Y. Y. Enakieva, M. Volostnykh, A. Sinelshchikova, I. A. Abdulaeva, K. P. Birin, A. Tsivadze

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引用次数: 9

摘要

多孔金属-有机框架的独特性能使得人们对这类材料的设计和合成越来越感兴趣。有针对性地设计具有理想性能的金属有机框架的一般策略是选择最佳连接体，通常以多面体有机配体为代表。卟啉由于其可调的物理化学性质和广泛的大环修饰可能性而成为这种框架的有希望的构建块。近十年来卟啉功能化合成方法的发展，促进了作为金属有机骨架基础的四吡咯化学的快速发展。本文对卟啉类金属有机骨架的合成及其在现代材料科学中的应用前景进行了综述。参考书目包括262篇参考文献。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Porous porphyrin-based metal-organic frameworks: synthesis, structure, sorption properties and application prospects

The unique properties of porous metal-organic frameworks are responsible for the increasing research interest in the design and synthesis of this type of materials. A general strategy towards targeted design of metal-organic frameworks possessing desired properties is a choice of optimal linkers, which are usually represented by polytopic organic ligands. Porphyrins are promising building blocks for such frameworks due to their tunable physicochemical properties and wide possibilities of macrocycle modification. The achievements of the last decade in the development of synthetic approaches to porphyrin functionalization have promoted fast progress of tetrapyrrole chemistry as the basis of metal-organic frameworks. This review gives analysis of the current literature devoted to the synthesis of porphyrin-based metal-organic frameworks and the prospects for their application in modern materials science. The bibliography includes 262 references.

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来源期刊

Russian Chemical Reviews 化学-化学综合

CiteScore

13.00

自引率

5.20%

发文量

审稿时长

6-12 weeks

期刊介绍： Russian Chemical Reviews serves as a complete translation of the esteemed monthly review journal Uspekhi Khimii, which has been a prominent figure in Russian scientific journals since its establishment in 1932. It offers comprehensive access to the advancements made by chemists from Russia and other former Soviet Union countries. Established in 1932, Russian Chemical Reviews is committed to publishing timely and significant review articles encompassing various facets of modern chemistry, including chemical physics, physical chemistry, computational and theoretical chemistry, catalysis, coordination chemistry, analytical chemistry, organic, organometallic, and organoelement chemistry, chemistry of macromolecules, applied chemistry, biochemistry, bio-organic chemistry, biomolecular chemistry, medicinal chemistry, materials chemistry, nanochemistry, nanostructures, and environmental chemistry.