重氮甲烷催化不饱和化合物环丙烷化的研究进展

IF 7 2区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Reviews Pub Date : 2021-01-01 DOI:10.1070/RCR4982

L. Menchikov, E. V. Shulishov, Yu. V. Tomilov

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引用次数: 0

摘要

综合分析了近10 ~ 15年来有关重氮甲烷催化不饱和化合物环丙烷化的主要成果和发展趋势。人们的注意力集中在以钯化合物为基础的高效催化剂上。有关底物结构和催化剂组分性质对这些反应的区域选择性和立体选择性的影响的数据被系统化。介绍了几种具有工业应用前景的重氮甲烷安全制备方法的特点，包括膜技术和连续流原位制备方法。参考书目包括281篇参考文献。

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Recent advances in the catalytic cyclopropanation of unsaturated compounds with diazomethane

The main achievements and development trends of the past 10–15 years related to the catalytic cyclopropanation of unsaturated compounds with diazomethane are integrated and analyzed. The attention is focused on the most efficient catalysts based on palladium compounds. Data on the effects of substrate structure and nature of catalyst components on the regio- and stereoselectivity of these reactions are systematized. Characteristic features of safe methods for diazomethane generation are considered, including the use of membrane technologies and continuous-flow and in situ preparation methods, which have prospects for industrial application. The bibliography includes 281 references.

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来源期刊

Russian Chemical Reviews 化学-化学综合

CiteScore

13.00

自引率

5.20%

发文量

审稿时长

6-12 weeks

期刊介绍： Russian Chemical Reviews serves as a complete translation of the esteemed monthly review journal Uspekhi Khimii, which has been a prominent figure in Russian scientific journals since its establishment in 1932. It offers comprehensive access to the advancements made by chemists from Russia and other former Soviet Union countries. Established in 1932, Russian Chemical Reviews is committed to publishing timely and significant review articles encompassing various facets of modern chemistry, including chemical physics, physical chemistry, computational and theoretical chemistry, catalysis, coordination chemistry, analytical chemistry, organic, organometallic, and organoelement chemistry, chemistry of macromolecules, applied chemistry, biochemistry, bio-organic chemistry, biomolecular chemistry, medicinal chemistry, materials chemistry, nanochemistry, nanostructures, and environmental chemistry.