排放流系统中O21Δg和O21Σ+g的测量

R. Derwent, B. Thrush
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引用次数: 95

摘要

发现两个O21Δg在6340 A处的二模发光的绝对强度为16±4 [O21Δg]2 cm3 mol-1 s-1单位。能量池生成O21Σ+g, ν= 0和1的速率常数分别为(1.2±0.3)× 107和6 × 105 cm3 mol-1 s-1。O21Σ+g在壁上的去除部分是由扩散控制的,报道了H2O和H2对其失活的速率常数。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Measurements on O21Δg and O21Σ+g in discharge flow systems
The absolute intensity of dimole emission at 6340 A by two O21Δg is found to be 16±4 [O21Δg]2 in cm3 mol–1 s–1 units. The rate constants for their energy pooling to yield O21Σ+g, ν= 0 and 1 are (1.2±0.3)× 107 and 6 × 105 cm3 mol–1 s–1 respectively. The removal of O21Σ+g at the walls is partly diffusion controlled, rate constants for its deactivation by H2O and H2 are reported.
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