{"title":"表面原子的复合。12个部分。-某些金属和合金表面的氮原子","authors":"M. L. Rahman, J. Linnett","doi":"10.1039/TF9716700183","DOIUrl":null,"url":null,"abstract":"The recombination coefficients for the recombination of nitrogen atoms on the surface of a number of metals and alloys have been measured using Smith's side-arm method. The constancy of activity for palladium, silver and a 50/50 alloys shows that d-band vacancies are unimportant. The results for Fe, Ni, Cu and Ni/Cu alloys suggest that with these materials a surface nitrate is formed and its properties are important in controlling the activity.","PeriodicalId":23290,"journal":{"name":"Transactions of The Faraday Society","volume":"67 1","pages":"183-190"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/TF9716700183","citationCount":"12","resultStr":"{\"title\":\"Recombination of atoms at surfaces. Part 12.—Nitrogen atoms at some metal and alloy surfaces\",\"authors\":\"M. L. Rahman, J. Linnett\",\"doi\":\"10.1039/TF9716700183\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The recombination coefficients for the recombination of nitrogen atoms on the surface of a number of metals and alloys have been measured using Smith's side-arm method. The constancy of activity for palladium, silver and a 50/50 alloys shows that d-band vacancies are unimportant. The results for Fe, Ni, Cu and Ni/Cu alloys suggest that with these materials a surface nitrate is formed and its properties are important in controlling the activity.\",\"PeriodicalId\":23290,\"journal\":{\"name\":\"Transactions of The Faraday Society\",\"volume\":\"67 1\",\"pages\":\"183-190\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1039/TF9716700183\",\"citationCount\":\"12\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Transactions of The Faraday Society\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/TF9716700183\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transactions of The Faraday Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/TF9716700183","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Recombination of atoms at surfaces. Part 12.—Nitrogen atoms at some metal and alloy surfaces
The recombination coefficients for the recombination of nitrogen atoms on the surface of a number of metals and alloys have been measured using Smith's side-arm method. The constancy of activity for palladium, silver and a 50/50 alloys shows that d-band vacancies are unimportant. The results for Fe, Ni, Cu and Ni/Cu alloys suggest that with these materials a surface nitrate is formed and its properties are important in controlling the activity.
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