室温下光诱导钴催化二芳胺的好氧N - N偶联

IF 2.8 4区化学 Q1 CHEMISTRY, ORGANIC

Asian Journal of Organic Chemistry Pub Date : 2022-12-01 DOI:10.1002/ajoc.202200553

Guanzhong Luo , Yu Han , Ruohan Zhang , Dongmiao Ding , Prof. Dr. Longyang Dian

引用次数: 1

摘要

我们在此报道了光诱导Co催化二芳胺的好氧N - N偶联，形成相应的四芳基肼。在光(390 ~ 395 nm)的照射下，在Co(OAc)2⋅4H2O和BPhen存在的温和条件下，可以实现N−N的偶联反应。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Photo‐induced Cobalt‐catalyzed Aerobic N−N Coupling of Diarylamines at Room Temperature

We report herein a photo induced Co‐catalyzed aerobic N−N coupling of diarylamines to form the corresponding tetraarylhydrazines. In this protocol, the N−N coupling reactions could be realized under mild conditions in the presence of Co(OAc)₂ ⋅ 4H₂O and BPhen with the irradiation of light (390–395 nm).

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来源期刊

Asian Journal of Organic Chemistry CHEMISTRY, ORGANIC-

CiteScore

4.70

自引率

3.70%

发文量

372

期刊介绍： Organic chemistry is the fundamental science that stands at the heart of chemistry, biology, and materials science. Research in these areas is vigorous and truly international, with three major regions making almost equal contributions: America, Europe and Asia. Asia now has its own top international organic chemistry journal—the Asian Journal of Organic Chemistry (AsianJOC) The AsianJOC is designed to be a top-ranked international research journal and publishes primary research as well as critical secondary information from authors across the world. The journal covers organic chemistry in its entirety. Authors and readers come from academia, the chemical industry, and government laboratories.