Arnaud Plassais , Marie-Pierre Pomiès , Nicolas Lequeux , Philippe Boch , Jean-Pierre Korb , Dominique Petit
{"title":"水化水泥浆体微孔大小的核磁共振分析","authors":"Arnaud Plassais , Marie-Pierre Pomiès , Nicolas Lequeux , Philippe Boch , Jean-Pierre Korb , Dominique Petit","doi":"10.1016/S1387-1609(01)01328-7","DOIUrl":null,"url":null,"abstract":"<div><p>We present a time evolution of <sup>1</sup>H spin-lattice relaxation rates in the laboratory (1/<em>T</em><sub>1</sub>) and in the rotating (1/<em>T</em><sub>1ρ</sub>) frame of a synthetic cement paste. The typical results found for both rates allow us to follow the main hydration stages of the cement paste and the refinement of its microporosity. In particular the texturation of the porosity and the structuration of the surface of the material are evidenced on two model cement pastes. An interpretation in terms of fractal size distribution is considered as well as the effect of the curing temperature.</p></div>","PeriodicalId":100305,"journal":{"name":"Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry","volume":"4 11","pages":"Pages 805-808"},"PeriodicalIF":0.0000,"publicationDate":"2001-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1387-1609(01)01328-7","citationCount":"22","resultStr":"{\"title\":\"Micropore size analysis in hydrated cement paste by NMR\",\"authors\":\"Arnaud Plassais , Marie-Pierre Pomiès , Nicolas Lequeux , Philippe Boch , Jean-Pierre Korb , Dominique Petit\",\"doi\":\"10.1016/S1387-1609(01)01328-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>We present a time evolution of <sup>1</sup>H spin-lattice relaxation rates in the laboratory (1/<em>T</em><sub>1</sub>) and in the rotating (1/<em>T</em><sub>1ρ</sub>) frame of a synthetic cement paste. The typical results found for both rates allow us to follow the main hydration stages of the cement paste and the refinement of its microporosity. In particular the texturation of the porosity and the structuration of the surface of the material are evidenced on two model cement pastes. An interpretation in terms of fractal size distribution is considered as well as the effect of the curing temperature.</p></div>\",\"PeriodicalId\":100305,\"journal\":{\"name\":\"Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry\",\"volume\":\"4 11\",\"pages\":\"Pages 805-808\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2001-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S1387-1609(01)01328-7\",\"citationCount\":\"22\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1387160901013287\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1387160901013287","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Micropore size analysis in hydrated cement paste by NMR
We present a time evolution of 1H spin-lattice relaxation rates in the laboratory (1/T1) and in the rotating (1/T1ρ) frame of a synthetic cement paste. The typical results found for both rates allow us to follow the main hydration stages of the cement paste and the refinement of its microporosity. In particular the texturation of the porosity and the structuration of the surface of the material are evidenced on two model cement pastes. An interpretation in terms of fractal size distribution is considered as well as the effect of the curing temperature.