冻结离子溶液中的俘获电子ⅱ。电子陷阱的不对称性和弛豫

Radiation Physics and Chemistry (1977) Pub Date : 1985-01-01 DOI:10.1016/0146-5724(85)90109-8

Maria Hilczer , Witold M. Bartczak , Miroslaw Sopek

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引用次数: 1

摘要

应用冻结离子溶液中电子定域的理论模型，研究了陷阱畸变对陷阱中电子能级的影响。发现非对称圈闭比对称圈闭略浅。然后用扭曲离子阱的弛豫解释了脉冲辐射分解和γ-辐射分解得到的电子吸收谱之间的差异。

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Trapped electron in frozen ionic solutions—II. Asymmetry and relaxation of electron traps

The theoretical model of the electron localized in frozen ionic solutions has been applied to investigate the influence of the trap distortion on the electron energy levels in the trap. It has been found that asymmetric traps are slightly more shallow than the symmetrical trap. The differences between electron absorption spectra obtained by pulse radiolysis and those by γ-radiolysis are then explained in terms of the relaxation of distorted ionic traps.

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Radiation Physics and Chemistry (1977)

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