Pan-Lei Xiao, Jia Gu, Da-Yong Peng, Wan-Ming Xiong, Xu-Liang Nie
{"title":"4-羧基甲氧基-3-苯基丙烯酸配体组装两种Cd(II)配位聚合物的合成及晶体结构","authors":"Pan-Lei Xiao, Jia Gu, Da-Yong Peng, Wan-Ming Xiong, Xu-Liang Nie","doi":"10.1007/s10870-022-00938-0","DOIUrl":null,"url":null,"abstract":"<div><p>Two Cd(II) complexes, [Cd(CMOPAA)(Phen)(H<sub>2</sub>O)]<sub>n</sub> (<b>1</b>) and [Cd(CMOPAA)(Bipy)]<sub>n</sub> (<b>2</b>), (H<sub>2</sub>CMOPAA = 4-carboxymethoxy-3-phenylacrylic acid, Phen = 1,10-phenanthroline and 2,2′-bipyridine = Bipy) were synthesized with 4-carboxymethoxy-3-phenylacrylic acid ligands by solvothermal condition and structurally characterized by element analysis, IR, TGA and single crystal X-ray diffraction. Complex <b>1</b> crystalizes in the monoclinic system, space group <i>C2/c</i> with<i> a</i> = 12.4609 (11) Å, <i>b</i> = 18.7973 (16) Å, <i>c</i> = 13.4544 (12) Å, <i>β</i> = 99.732 (1)°, <i>V</i> = 3106.1 (5) Å<sup>3</sup>. The asymmetric unit of complex <b>1</b> consists of one Cd(II) ion, one CMOPAA<sup>2−</sup> ligand, one Phen ligand and one H<sub>2</sub>O. Cd(II) ion is an eight-coordinated distorted dodecahedron geometry. Each CMOPAA<sup>2−</sup> ligand coordinates with two adjacent Cd(II) ions to form a one-dimensional chain. Complex <b>2</b> crystalizes in the triclinic system, space group <i>P</i>-<i>1</i> with<i> a</i> = 9.407 (3) Å, <i>b</i> = 9.838 (3) Å, <i>c</i> = 11.792 (4) Å, <i>α</i> = 83.974 (4)°, <i>β</i> = 78.392 (3)°, <i>γ</i> = 67.019 (3)°, <i>V</i> = 983.7 (5) Å<sup>3</sup>. The asymmetric unit of complex <b>2</b> consists of one Cd(II) ion, one CMOPAA<sup>2−</sup> ligand and one Bipy ligand. Cd(II) ion is a seven-coordinated twisted single-cap triangular prism configuration. The hexadentate bridging CMOPAA<sup>2−</sup> ligands coordinates with four adjacent Cd(II) ions to form a one-dimensional chain. The tetradentate bridging CMOPAA<sup>2−</sup> ligands link the neighboring one-dimensional chains to form a novel two-dimensional network structure.</p><h3>Graphical Abstract</h3><p>Two Cd(II) complexes, [Cd(CMOPAA)(Phen)(H<sub>2</sub>O)]<sub>n</sub> (<b>1</b>) and [Cd(CMOPAA)(Bipy)]<sub>n</sub> (<b>2</b>), (H<sub>2</sub>CMOPAA = 4-carboxymethoxy-3-phenylacrylic acid, Phen = 1,10-phenanthroline and 2,2′-bipyridine = Bipy) were synthesized with 4-carboxymethoxy-3-phenylacrylic acid ligands and structurally characterized by element analysis, IR, TGA and single crystal X-ray diffraction. Complex <b>1</b> is a one-dimensional chain and complex <b>2</b> is a two-dimensional network structure.</p>\n <figure><div><div><div><picture><source><img></source></picture></div></div></div></figure>\n </div>","PeriodicalId":615,"journal":{"name":"Journal of Chemical Crystallography","volume":"53 1","pages":"16 - 24"},"PeriodicalIF":0.4000,"publicationDate":"2022-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10870-022-00938-0.pdf","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Crystal Structures of Two Cd(II) Coordination Polymers Assembled by 4-Carboxymethoxy-3-phenylacrylic Acid Ligands\",\"authors\":\"Pan-Lei Xiao, Jia Gu, Da-Yong Peng, Wan-Ming Xiong, Xu-Liang Nie\",\"doi\":\"10.1007/s10870-022-00938-0\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Two Cd(II) complexes, [Cd(CMOPAA)(Phen)(H<sub>2</sub>O)]<sub>n</sub> (<b>1</b>) and [Cd(CMOPAA)(Bipy)]<sub>n</sub> (<b>2</b>), (H<sub>2</sub>CMOPAA = 4-carboxymethoxy-3-phenylacrylic acid, Phen = 1,10-phenanthroline and 2,2′-bipyridine = Bipy) were synthesized with 4-carboxymethoxy-3-phenylacrylic acid ligands by solvothermal condition and structurally characterized by element analysis, IR, TGA and single crystal X-ray diffraction. Complex <b>1</b> crystalizes in the monoclinic system, space group <i>C2/c</i> with<i> a</i> = 12.4609 (11) Å, <i>b</i> = 18.7973 (16) Å, <i>c</i> = 13.4544 (12) Å, <i>β</i> = 99.732 (1)°, <i>V</i> = 3106.1 (5) Å<sup>3</sup>. The asymmetric unit of complex <b>1</b> consists of one Cd(II) ion, one CMOPAA<sup>2−</sup> ligand, one Phen ligand and one H<sub>2</sub>O. Cd(II) ion is an eight-coordinated distorted dodecahedron geometry. Each CMOPAA<sup>2−</sup> ligand coordinates with two adjacent Cd(II) ions to form a one-dimensional chain. Complex <b>2</b> crystalizes in the triclinic system, space group <i>P</i>-<i>1</i> with<i> a</i> = 9.407 (3) Å, <i>b</i> = 9.838 (3) Å, <i>c</i> = 11.792 (4) Å, <i>α</i> = 83.974 (4)°, <i>β</i> = 78.392 (3)°, <i>γ</i> = 67.019 (3)°, <i>V</i> = 983.7 (5) Å<sup>3</sup>. The asymmetric unit of complex <b>2</b> consists of one Cd(II) ion, one CMOPAA<sup>2−</sup> ligand and one Bipy ligand. Cd(II) ion is a seven-coordinated twisted single-cap triangular prism configuration. The hexadentate bridging CMOPAA<sup>2−</sup> ligands coordinates with four adjacent Cd(II) ions to form a one-dimensional chain. The tetradentate bridging CMOPAA<sup>2−</sup> ligands link the neighboring one-dimensional chains to form a novel two-dimensional network structure.</p><h3>Graphical Abstract</h3><p>Two Cd(II) complexes, [Cd(CMOPAA)(Phen)(H<sub>2</sub>O)]<sub>n</sub> (<b>1</b>) and [Cd(CMOPAA)(Bipy)]<sub>n</sub> (<b>2</b>), (H<sub>2</sub>CMOPAA = 4-carboxymethoxy-3-phenylacrylic acid, Phen = 1,10-phenanthroline and 2,2′-bipyridine = Bipy) were synthesized with 4-carboxymethoxy-3-phenylacrylic acid ligands and structurally characterized by element analysis, IR, TGA and single crystal X-ray diffraction. Complex <b>1</b> is a one-dimensional chain and complex <b>2</b> is a two-dimensional network structure.</p>\\n <figure><div><div><div><picture><source><img></source></picture></div></div></div></figure>\\n </div>\",\"PeriodicalId\":615,\"journal\":{\"name\":\"Journal of Chemical Crystallography\",\"volume\":\"53 1\",\"pages\":\"16 - 24\"},\"PeriodicalIF\":0.4000,\"publicationDate\":\"2022-03-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://link.springer.com/content/pdf/10.1007/s10870-022-00938-0.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Chemical Crystallography\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10870-022-00938-0\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CRYSTALLOGRAPHY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical Crystallography","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10870-022-00938-0","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
Synthesis and Crystal Structures of Two Cd(II) Coordination Polymers Assembled by 4-Carboxymethoxy-3-phenylacrylic Acid Ligands
Two Cd(II) complexes, [Cd(CMOPAA)(Phen)(H2O)]n (1) and [Cd(CMOPAA)(Bipy)]n (2), (H2CMOPAA = 4-carboxymethoxy-3-phenylacrylic acid, Phen = 1,10-phenanthroline and 2,2′-bipyridine = Bipy) were synthesized with 4-carboxymethoxy-3-phenylacrylic acid ligands by solvothermal condition and structurally characterized by element analysis, IR, TGA and single crystal X-ray diffraction. Complex 1 crystalizes in the monoclinic system, space group C2/c with a = 12.4609 (11) Å, b = 18.7973 (16) Å, c = 13.4544 (12) Å, β = 99.732 (1)°, V = 3106.1 (5) Å3. The asymmetric unit of complex 1 consists of one Cd(II) ion, one CMOPAA2− ligand, one Phen ligand and one H2O. Cd(II) ion is an eight-coordinated distorted dodecahedron geometry. Each CMOPAA2− ligand coordinates with two adjacent Cd(II) ions to form a one-dimensional chain. Complex 2 crystalizes in the triclinic system, space group P-1 with a = 9.407 (3) Å, b = 9.838 (3) Å, c = 11.792 (4) Å, α = 83.974 (4)°, β = 78.392 (3)°, γ = 67.019 (3)°, V = 983.7 (5) Å3. The asymmetric unit of complex 2 consists of one Cd(II) ion, one CMOPAA2− ligand and one Bipy ligand. Cd(II) ion is a seven-coordinated twisted single-cap triangular prism configuration. The hexadentate bridging CMOPAA2− ligands coordinates with four adjacent Cd(II) ions to form a one-dimensional chain. The tetradentate bridging CMOPAA2− ligands link the neighboring one-dimensional chains to form a novel two-dimensional network structure.
Graphical Abstract
Two Cd(II) complexes, [Cd(CMOPAA)(Phen)(H2O)]n (1) and [Cd(CMOPAA)(Bipy)]n (2), (H2CMOPAA = 4-carboxymethoxy-3-phenylacrylic acid, Phen = 1,10-phenanthroline and 2,2′-bipyridine = Bipy) were synthesized with 4-carboxymethoxy-3-phenylacrylic acid ligands and structurally characterized by element analysis, IR, TGA and single crystal X-ray diffraction. Complex 1 is a one-dimensional chain and complex 2 is a two-dimensional network structure.
期刊介绍：
Journal of Chemical Crystallography is an international and interdisciplinary publication dedicated to the rapid dissemination of research results in the general areas of crystallography and spectroscopy. Timely research reports detail topics in crystal chemistry and physics and their relation to problems of molecular structure; structural studies of solids, liquids, gases, and solutions involving spectroscopic, spectrometric, X-ray, and electron and neutron diffraction; and theoretical studies.
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