二茂铁+氰酸酯体系的光诱导过程

IF 1 4区化学 Q4 POLYMER SCIENCE

Polymer Science, Series B Pub Date : 2022-08-31 DOI:10.1134/S1560090422700312

D. A. Gurov, E. S. Sorin, G. F. Novikov

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引用次数: 0

摘要

研究了双酚А双氰酸酯低聚物中二茂铁在紫外光下解离的动力学过程。利用动力学数据计算了速率常数，并对系统中发生的光化学反应机理作了假设。由于在低聚物混合物中存在氰酸酯亚氨基甲酸酯衍生物，二茂铁在中波紫外线照射下光解成为可能。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Photoinduced Processes in System Ferrocene + Cyanate Ester

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Photoinduced Processes in System Ferrocene + Cyanate Ester

The kinetics of processes related to the dissociation of ferrocene in bisphenol А dicyanate oligomer under UV light is studied. Using the kinetic data rate constants are calculated and assumption regarding the mechanism of photochemical reactions occurring in the system is made. The photodissociation of ferrocene under medium-wave UV irradiation becomes possible due to the presence of cyanate ester iminocarbamate derivatives in the oligomer mixture.

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来源期刊

Polymer Science, Series B 化学-高分子科学

CiteScore

1.80

自引率

8.30%

发文量

审稿时长

>0 weeks

期刊介绍： Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed