含叔胺甲基丙烯酸缩水甘油酯共聚物薄膜的低温水化学功能化引发CVD研究

Chemical Vapor Deposition Pub Date : 2014-10-24 DOI:10.1002/cvde.201407129

Fatma Sarıipek, Mustafa Karaman

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引用次数: 12

摘要

本文报道了用引发(i)CVD法合成甲基丙烯酸缩水甘油酯与甲基丙烯酸二乙胺乙酯共聚物薄膜。叔胺官能团加入共聚物膜的目的是在良性条件下加快环氧基团亲核开环反应的速率。研究发现，叔胺官能团在聚甲基丙烯酸缩水甘油酯(PGMA)薄膜中的作用显著提高了开环反应的速率和程度。在室温下反应2小时后，72%的环氧基被消耗，而在类似条件下，PGMA薄膜的转化率可以忽略不计。

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Initiated CVD of Tertiary Amine-Containing Glycidyl Methacrylate Copolymer Thin Films for Low Temperature Aqueous Chemical Functionalization†

This manuscript reports on the synthesis of copolymer films of glycidyl methacrylate with diethylaminoethyl methacrylate by initiated (i)CVD. The purpose of the incorporation of tertiary amine functionality in the copolymer film is to accelerate the rate of the nucleophilic ring-opening reaction of the epoxide group under benign conditions. It is found that tertiary amine functionality in the poly(glycidyl methacrylate) (PGMA) film significantly increases the rate and degree of the ring-opening reactions. After 2 h of reaction at room temperature, 72% of the epoxy groups are consumed, while the conversion under similar conditions is negligible for the PGMA film.

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来源期刊

Chemical Vapor Deposition 工程技术-材料科学：膜

自引率

0.00%

发文量

审稿时长

>12 weeks

期刊介绍： Chemical Vapor Deposition (CVD) publishes Reviews, Short Communications, and Full Papers on all aspects of chemical vapor deposition and related technologies, along with other articles presenting opinion, news, conference information, and book reviews. All papers are peer-reviewed. The journal provides a unified forum for chemists, physicists, and engineers whose publications on chemical vapor deposition have in the past been spread over journals covering inorganic chemistry, materials chemistry, organometallics, applied physics and semiconductor technology, thin films, and ceramic processing.