2-草四环[5.4.0.01,8.05,11]十一-9-烯衍生物的对映选择性填充柱SFC

The journal of microcolumn separations : JMS Pub Date : 2001-07-02 DOI:10.1002/mcs.1036

Koen Desmet, Pat Sandra, Kristóf Vízvárdi, Georges J. Hoornaert, Erik Van der Eycken

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引用次数: 2

摘要

直链淀粉的3,5-二甲基苯基氨基甲酸酯衍生物(Chiralpak AD)上的填充柱SFC (pSFC)对由取代的4-苯氧丁-1-烯的紫外辐射产生的2-草四环[5.4.0.01,8.05,11]十一-9-烯衍生物具有很高的对映选择性。相对于正相LC的分析速度和相对于毛细管GC的温和条件是pSFC分析这些不稳定产物的有价值的特征。©2001 John Wiley &[J]微型电子，2001年9月13日:163-168

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Enantioselective packed column SFC for the separation of 2-oxatetracyclo [5.4.0.01,8.05,11] undec-9-ene derivatives

Packed column SFC (pSFC) on a 3,5-dimethylphenylcarbamate derivative of amylose (Chiralpak AD) has exhibited high enantioselectivity for the separation of 2-oxatetracyclo [5.4.0.0^1,8.0^5,11] undec-9-ene derivatives resulting from the UV-radiation of substituted 4-phenoxybut-1-enes. The speed of analysis compared to normal phase LC and mild conditions compared to capillary GC were valuable characteristics of pSFC for the analysis of these labile products. © 2001 John Wiley & Sons, Inc. J Micro Sep 13: 163–168, 2001

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The journal of microcolumn separations : JMS

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