Yu. A. Teterin, M. N. Smirnova, K. I. Maslakov, A. Yu. Teterin, M. A. Kop’eva, G. E. Nikiforova, V. A. Ketsko
{"title":"凝胶燃烧制备Y2.5Ce0.5Fe2.5Ga2.5O12石榴铁粉末的离子和物相组成","authors":"Yu. A. Teterin, M. N. Smirnova, K. I. Maslakov, A. Yu. Teterin, M. A. Kop’eva, G. E. Nikiforova, V. A. Ketsko","doi":"10.1134/S0012501622040029","DOIUrl":null,"url":null,"abstract":"<p>The ionic and phase compositions of Y<sub>2.5</sub>Ce<sub>0.5</sub>Fe<sub>2.5</sub>Ga<sub>2.5</sub>O<sub>12</sub> ferrogarnet samples obtained by gel combustion with subsequent vacuum annealing were studied for the first time by X-ray photoelectron spectroscopy and X-ray powder diffraction analysis. The X-ray powder diffraction data confirmed the phase homogeneity of Y<sub>2.5</sub>Ce<sub>0.5</sub>Fe<sub>2.5</sub>Ga<sub>2.5</sub>O<sub>12</sub> and the absence of a cerium dioxide impurity. At the same time, on the surface of Y<sub>2.5</sub>Ce<sub>0.5</sub>Fe<sub>2.5</sub>Ga<sub>2.5</sub>O<sub>12</sub> particles, along with Ce<sup>3+</sup>, there are Ce<sup>4+</sup> ions.</p>","PeriodicalId":532,"journal":{"name":"Doklady Physical Chemistry","volume":"503 2","pages":"45 - 49"},"PeriodicalIF":1.1000,"publicationDate":"2022-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Ionic and Phase Compositions of Y2.5Ce0.5Fe2.5Ga2.5O12 Ferrogarnet Powder Produced by Gel Combustion\",\"authors\":\"Yu. A. Teterin, M. N. Smirnova, K. I. Maslakov, A. Yu. Teterin, M. A. Kop’eva, G. E. Nikiforova, V. A. Ketsko\",\"doi\":\"10.1134/S0012501622040029\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The ionic and phase compositions of Y<sub>2.5</sub>Ce<sub>0.5</sub>Fe<sub>2.5</sub>Ga<sub>2.5</sub>O<sub>12</sub> ferrogarnet samples obtained by gel combustion with subsequent vacuum annealing were studied for the first time by X-ray photoelectron spectroscopy and X-ray powder diffraction analysis. The X-ray powder diffraction data confirmed the phase homogeneity of Y<sub>2.5</sub>Ce<sub>0.5</sub>Fe<sub>2.5</sub>Ga<sub>2.5</sub>O<sub>12</sub> and the absence of a cerium dioxide impurity. At the same time, on the surface of Y<sub>2.5</sub>Ce<sub>0.5</sub>Fe<sub>2.5</sub>Ga<sub>2.5</sub>O<sub>12</sub> particles, along with Ce<sup>3+</sup>, there are Ce<sup>4+</sup> ions.</p>\",\"PeriodicalId\":532,\"journal\":{\"name\":\"Doklady Physical Chemistry\",\"volume\":\"503 2\",\"pages\":\"45 - 49\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2022-06-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Doklady Physical Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0012501622040029\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Doklady Physical Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0012501622040029","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Ionic and Phase Compositions of Y2.5Ce0.5Fe2.5Ga2.5O12 Ferrogarnet Powder Produced by Gel Combustion
The ionic and phase compositions of Y2.5Ce0.5Fe2.5Ga2.5O12 ferrogarnet samples obtained by gel combustion with subsequent vacuum annealing were studied for the first time by X-ray photoelectron spectroscopy and X-ray powder diffraction analysis. The X-ray powder diffraction data confirmed the phase homogeneity of Y2.5Ce0.5Fe2.5Ga2.5O12 and the absence of a cerium dioxide impurity. At the same time, on the surface of Y2.5Ce0.5Fe2.5Ga2.5O12 particles, along with Ce3+, there are Ce4+ ions.
期刊介绍:
Doklady Physical Chemistry is a monthly journal containing English translations of current Russian research in physical chemistry from the Physical Chemistry sections of the Doklady Akademii Nauk (Proceedings of the Russian Academy of Sciences). The journal publishes the most significant new research in physical chemistry being done in Russia, thus ensuring its scientific priority. Doklady Physical Chemistry presents short preliminary accounts of the application of the state-of-the-art physical chemistry ideas and methods to the study of organic and inorganic compounds and macromolecules; polymeric, inorganic and composite materials as well as corresponding processes. The journal is intended for scientists in all fields of chemistry and in interdisciplinary sciences.