{"title":"查尔酮取代含噻吩单元的锌(II)和镁(II)金属酞菁的光物理、光化学性质","authors":"Ayse Aktas Kamiloglu, Ipek Omeroglu, Halise Yalazan, Mahmut Durmus, Gonca Celik, Halit Kantekin","doi":"10.1007/s10847-022-01152-3","DOIUrl":null,"url":null,"abstract":"<div><p>The novel thiophene-chalcone compound (<b>2</b>), phthalonitrile derivatives bearing thiophene-chalcone group (<b>3</b> and <b>4</b>) and their zinc (II) (ZnPcs) (<b>3a</b> and <b>4a</b>) and magnesium (II) (MgPcs) (<b>3b</b> and <b>4b</b>) phthalocyanine compounds were synthesized in this study. The structure of all these new compounds were elucidated by spectroscopic techniques like IR, <sup>1</sup> H NMR, <sup>13</sup> C NMR (for compounds <b>2, 3</b> and <b>4)</b>, MALDI–TOF mass and UV-Vis. The fluorescence quantum yields and lifetimes (photophysical properties), and the singlet oxygen and photodegradation quantum yields (photochemical properties) of thiophene bearing chalcone substituted ZnPcs (<b>3a</b> and <b>4a</b>) and MgPcs (<b>3b</b> and <b>4b</b>) were studied in DMSO (dimethylsulfoxide) to determine if they are convenient photosensitizers for photodynamic therapy (PDT) applications.</p></div>","PeriodicalId":54324,"journal":{"name":"Journal of Inclusion Phenomena and Macrocyclic Chemistry","volume":"102 7-8","pages":"693 - 703"},"PeriodicalIF":1.7000,"publicationDate":"2022-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Photophysical, photochemical properties of chalcone substituted Zinc(II) and Magnesium(II) metallophthalocyanines bearing thiophene units\",\"authors\":\"Ayse Aktas Kamiloglu, Ipek Omeroglu, Halise Yalazan, Mahmut Durmus, Gonca Celik, Halit Kantekin\",\"doi\":\"10.1007/s10847-022-01152-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The novel thiophene-chalcone compound (<b>2</b>), phthalonitrile derivatives bearing thiophene-chalcone group (<b>3</b> and <b>4</b>) and their zinc (II) (ZnPcs) (<b>3a</b> and <b>4a</b>) and magnesium (II) (MgPcs) (<b>3b</b> and <b>4b</b>) phthalocyanine compounds were synthesized in this study. The structure of all these new compounds were elucidated by spectroscopic techniques like IR, <sup>1</sup> H NMR, <sup>13</sup> C NMR (for compounds <b>2, 3</b> and <b>4)</b>, MALDI–TOF mass and UV-Vis. The fluorescence quantum yields and lifetimes (photophysical properties), and the singlet oxygen and photodegradation quantum yields (photochemical properties) of thiophene bearing chalcone substituted ZnPcs (<b>3a</b> and <b>4a</b>) and MgPcs (<b>3b</b> and <b>4b</b>) were studied in DMSO (dimethylsulfoxide) to determine if they are convenient photosensitizers for photodynamic therapy (PDT) applications.</p></div>\",\"PeriodicalId\":54324,\"journal\":{\"name\":\"Journal of Inclusion Phenomena and Macrocyclic Chemistry\",\"volume\":\"102 7-8\",\"pages\":\"693 - 703\"},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2022-06-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Inclusion Phenomena and Macrocyclic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10847-022-01152-3\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Inclusion Phenomena and Macrocyclic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10847-022-01152-3","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Photophysical, photochemical properties of chalcone substituted Zinc(II) and Magnesium(II) metallophthalocyanines bearing thiophene units
The novel thiophene-chalcone compound (2), phthalonitrile derivatives bearing thiophene-chalcone group (3 and 4) and their zinc (II) (ZnPcs) (3a and 4a) and magnesium (II) (MgPcs) (3b and 4b) phthalocyanine compounds were synthesized in this study. The structure of all these new compounds were elucidated by spectroscopic techniques like IR, 1 H NMR, 13 C NMR (for compounds 2, 3 and 4), MALDI–TOF mass and UV-Vis. The fluorescence quantum yields and lifetimes (photophysical properties), and the singlet oxygen and photodegradation quantum yields (photochemical properties) of thiophene bearing chalcone substituted ZnPcs (3a and 4a) and MgPcs (3b and 4b) were studied in DMSO (dimethylsulfoxide) to determine if they are convenient photosensitizers for photodynamic therapy (PDT) applications.
期刊介绍：
The Journal of Inclusion Phenomena and Macrocyclic Chemistry is the premier interdisciplinary publication reporting on original research into all aspects of host-guest systems. Examples of specific areas of interest are: the preparation and characterization of new hosts and new host-guest systems, especially those involving macrocyclic ligands; crystallographic, spectroscopic, thermodynamic and theoretical studies; applications in chromatography and inclusion polymerization; enzyme modelling; molecular recognition and catalysis by inclusion compounds; intercalates in biological and non-biological systems, cyclodextrin complexes and their applications in the agriculture, flavoring, food and pharmaceutical industries; synthesis, characterization and applications of zeolites.
The journal publishes primarily reports of original research and preliminary communications, provided the latter represent a significant advance in the understanding of inclusion science. Critical reviews dealing with recent advances in the field are a periodic feature of the journal.
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