Pan-Pan Luo, Xin-Zhong Li, Bei-Bei Qu, Han-Yu Xue, Yan-Hui Yang
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Solar-driven seawater production H2O2 catalyzed by hydroxyl functionalized crystalline K-doped g-C3N4 under ambient conditions
Three hydroxyl functionalized crystalline K-doped g-C3N4 were synthesized from dicyandiamide, melamine, ammonium chloride, ammonium oxalate, and ammonium citrate via ionothermal polycondensation using KCl as molten salt under N2 atmosphere, which served as efficient recyclable photocatalysis realized that generating H2O2 directly from seawater with air by 2e− ORR pathway under stimulated solar irradiation in ambient conditions. Under optimized conditions, the highest H2O2 production rate of 1622 μmol g−1 h−1 for duration of 10 h was obtained. The cycling performances of HPCN-2 displayed reusable for five times without noticeably loss of its catalytic activity. This work presents a real safer, sustainable, and economical approach for production of H2O2 directly from abundant natural seawater.
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All new compounds should be satisfactorily identified and proof of their structure given according to generally accepted standards. Structural reports, such as papers exclusively dealing with synthesis and characterization, analytical techniques, or X-ray diffraction studies of metal-organic or organometallic compounds will not be considered. The editors reserve the right to refuse without peer review any manuscript that does not comply with the aims and scope of the journal. Applied Organometallic Chemistry publishes Full Papers, Reviews, Mini Reviews and Communications of scientific research in all areas of organometallic and metal-organic chemistry involving main group metals, transition metals, lanthanides and actinides. All contributions should contain an explicit application of novel compounds, for instance in materials science, nano science, catalysis, chemical vapour deposition, metal-mediated organic synthesis, polymers, bio-organometallics, metallo-therapy, metallo-diagnostics and medicine. Reviews of books covering aspects of the fields of focus are also published.
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