固定在彩色捕集器®上的卟啉:用于将胺转化为亚胺和将醛转化为羧酸的光活性材料

Dr. Caterina Damiano, Matteo Cavalleri, Prof. Corrado di Natale', Prof. Roberto Paolesse, Prof. Emma Gallo
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引用次数: 0

摘要

通过将卟啉锌(II)非均相化到基于纤维素的Colour Catcher®片材上,获得了一种新的光活性材料。在白光存在下,如此获得的Zn(卟啉)@CC材料在胺与亚胺的光氧化偶联和醛与相应酸的光氧化中表现非常好地活化分子氧。固体载体的高生态相容性、光活性材料的化学稳定性和所应用的温和实验条件赋予了该程序非常好的可持续性,并为在光介导的反应中更多地使用基于Colour Catcher®的卟啉材料打开了大门。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Porphyrins Anchored onto Colour Catcher®: Photoactive Material for the Conversion of Amines into Imines and Aldehydes into Carboxylic Acids

Porphyrins Anchored onto Colour Catcher®: Photoactive Material for the Conversion of Amines into Imines and Aldehydes into Carboxylic Acids

A new photoactive material was obtained by the heterogenization of zinc(II) porphyrin onto cellulose-based Colour Catcher® sheet. The so-obtained Zn(porphyrin)@CC material performed very well in activating molecular oxygen in the photooxidative coupling of amines to imines and the photooxidation of aldehydes to corresponding acids in the presence of white light. The high eco-compatibility of the solid support, the chemical stability of the photoactive material and the mild experimental conditions applied confer a very good sustainability to the procedure and open the doors to a larger employment of Colour Catcher®-based porphyrin material in reactions mediated by light.

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