硫化学的作用。有机合成的新前景

IF 1.4 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2023-01-01 DOI:10.1080/10426507.2023.2173755

Samir Z. Zard

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引用次数: 0

摘要

以有机硫衍生物为基础的自由基化学是解决合成问题的有力工具。本文简要介绍了三取代环烯烃成不稳定的二取代区域异构体的反热力学异构化方法。它还描述了黄原酸盐作为合成和修饰酮的自由基前体以及获取广泛的硼酸盐的使用。

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Sulfur chemistry in action. New perspectives for organic synthesis

Abstract The radical chemistry based on organosulfur derivatives constitutes a powerful tool for solving synthetic problems. The present short overview discusses a method for the contra-thermodynamic isomerization of trisubstituted cycloalkenes into the less stable disubstituted regioisomer. It also describes the use of xanthates as radical precursors for the synthesis and modification of ketones and for accessing a wide range of boronates. Graphical Abstract

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来源期刊

Phosphorus, Sulfur, and Silicon and the Related Elements 化学-无机化学与核化学

CiteScore

2.60

自引率

7.70%

发文量

103

审稿时长

2.1 months

期刊介绍： Phosphorus, Sulfur, and Silicon and the Related Elements is a monthly publication intended to disseminate current trends and novel methods to those working in the broad and interdisciplinary field of heteroatom chemistry.