用Phy-X程序研究Ag、Cd、Zn掺杂硼酸锂玻璃的伽马射线屏蔽特性

IF 2.7 4区 材料科学 Q1 MATERIALS SCIENCE, CERAMICS
Mario César Pérez Chávez , Janet Alejandra Elías Ángel , Christian Gómez-Solís , Ramón Castañeda-Priego , Héctor René Vega Carrillo , Modesto Antonio Sosa Aquino , Miguel Ángel Vallejo Hernández
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引用次数: 0

摘要

采用熔融淬火法制备了掺有Ag、Cd和Zn三种过渡金属的硼酸锂玻璃。掺杂剂浓度为(Li2B4O7)(100−x)(Zn[NO3]2,CdN2O6,AgNO3)(x=0%,1%,5%)。对掺杂玻璃进行了分析,确定了掺杂玻璃的屏蔽特性。XRD测量显示了玻璃的非晶态。荧光分析显示了Ag、Cd和Zn的特征发射及其增强作用。在200–900 nm的间隔内记录了紫外-可见光谱,并显示了属于三种过渡金属的等离子体激元的峰。使用Tauc的图模型计算光能带隙;并计算了折射率。此外,作为样品表征的一部分,还计算了密度(ρ)和摩尔体积(Vm)。为了确定伽马射线的屏蔽特性,使用Phy-X程序确定0.015至15MeV光子的质量衰减系数(μ/ρ)(E)、半值层(HVL(E))和有效原子序数(Zeff(E)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Gamma-ray shielding features of lithium borate glass doped with Ag, Cd and Zn using Phy-X program

Lithium borate glasses doped with three transition metals: Ag, Cd and Zn were prepared with the melt-quenching method. Dopants concentrations were (Li2B4O7)(100−x) (Zn[NO3]2, CdN2O6, AgNO3) (x = 0%, 1%, 5%). Doped glasses were analyzed and their shielding features were determined. The XRD measurements show the amorphous state of the glasses. Fluorescence analysis shows the characteristic emission of Ag, Cd and Zn and their enhancement is explained. UV–vis spectra were recorded in the interval 200–900 nm, and show the peaks belonging to the plasmon of the three transition metals. The optical energy band gaps were calculated using the Tauc's plot model; also, the refractive index was calculated. Additionally, density (ρ) and molar volume (Vm) were calculated as part of the characterization of the samples. In order to determine the shielding features against gamma-rays the mass attenuation coefficient (μ/ρ)(E), the half value layer (HVL(E)) and the Effective Atomic Number (Zeff(E)) for photons from 0.015 to 15 MeV using the Phy-X program.

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来源期刊
Boletin de la Sociedad Espanola de Ceramica y Vidrio
Boletin de la Sociedad Espanola de Ceramica y Vidrio 工程技术-材料科学:硅酸盐
CiteScore
5.50
自引率
2.90%
发文量
72
审稿时长
103 days
期刊介绍: The Journal of the Spanish Ceramic and Glass Society publishes scientific articles and communications describing original research and reviews relating to ceramic materials and glasses. The main interests are on novel generic science and technology establishing the relationships between synthesis, processing microstructure and properties of materials. Papers may deal with ceramics and glasses included in any of the conventional categories: structural, functional, traditional, composites and cultural heritage. The main objective of the Journal of the Spanish Ceramic and Glass Society is to sustain a high standard research quality by means of appropriate reviewing procedures.
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