含硫油微量元素组成中钒占主导地位的可能原因

IF 0.7 Q4 CHEMISTRY, MULTIDISCIPLINARY

Moscow University Chemistry Bulletin Pub Date : 2023-03-25 DOI:10.3103/S0027131422070094

G. V. Lisichkin

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引用次数: 0

摘要

根据石油成因的非生物成因假说，由于地球脱气，特别是地幔甲烷及其缩聚产物与单质硫的相互作用而形成的矿床是热力学开放体系。在开放系统中，自组织过程得以实现，碱性反应的催化剂发生逐步演化，并伴随着其活性的增加和在系统中的积累。钒在酸性油微量元素组成中占主导地位可能是由于其在C-S键形成的碱性反应中具有催化活性。

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A Possible Reason for the Predomination of Vanadium in the Microelement Composition of Sulfurous Oils

In accordance with the abiogenic hypothesis of the origin of oil, deposits formed as a result of degassing of the Earth, in particular, due to the interaction of mantle methane and its polycondensation products with elemental sulfur, are thermodynamically open systems. In open systems, self-organization processes are realized and a progressive evolution of the catalyst of the basic reaction occurs, accompanied by an increase in its activity and accumulation in the system. The predominance of vanadium in the trace element composition of sour oils may be due to its catalytic activity in the basic reaction of the formation of C–S bonds.

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来源期刊

Moscow University Chemistry Bulletin CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

1.30

自引率

14.30%

发文量

期刊介绍： Moscow University Chemistry Bulletin is a journal that publishes review articles, original research articles, and short communications on various areas of basic and applied research in chemistry, including medical chemistry and pharmacology.