{"title":"三取代烯烃的有机催化不对称溴羟基化反应","authors":"Jing Li, Zhanwei Wang, Xiaoyu Wang, Yian Shi","doi":"10.1016/j.tchem.2023.100039","DOIUrl":null,"url":null,"abstract":"<div><p>This work describes an effective enantioselective bromohydroxylation of <em>tri</em>-substituted alkenes with (DHQD)<sub>2</sub>PHAL as catalyst and H<sub>2</sub>O as nucleophile, providing a variety of corresponding optically active bromohydrins with up to 95% ee.</p></div>","PeriodicalId":74918,"journal":{"name":"Tetrahedron chem","volume":"6 ","pages":"Article 100039"},"PeriodicalIF":0.0000,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Organocatalytic asymmetric bromohydroxylation of tri-substituted alkenes\",\"authors\":\"Jing Li, Zhanwei Wang, Xiaoyu Wang, Yian Shi\",\"doi\":\"10.1016/j.tchem.2023.100039\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This work describes an effective enantioselective bromohydroxylation of <em>tri</em>-substituted alkenes with (DHQD)<sub>2</sub>PHAL as catalyst and H<sub>2</sub>O as nucleophile, providing a variety of corresponding optically active bromohydrins with up to 95% ee.</p></div>\",\"PeriodicalId\":74918,\"journal\":{\"name\":\"Tetrahedron chem\",\"volume\":\"6 \",\"pages\":\"Article 100039\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Tetrahedron chem\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2666951X23000050\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Tetrahedron chem","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666951X23000050","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Organocatalytic asymmetric bromohydroxylation of tri-substituted alkenes
This work describes an effective enantioselective bromohydroxylation of tri-substituted alkenes with (DHQD)2PHAL as catalyst and H2O as nucleophile, providing a variety of corresponding optically active bromohydrins with up to 95% ee.
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