协同相互作用对铁(II)配合物中自旋交叉现象的影响

IF 0.7 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Theoretical and Experimental Chemistry Pub Date : 2022-08-25 DOI:10.1007/s11237-022-09725-6

M. L. Seredyuk, K. O. Znovjyak, I. O. Fritsky

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引用次数: 0

摘要

总结了赝八面体铁配合物中自旋跃迁现象的理论原理。考虑了在外界因素作用下中心离子d轨道间电子的本征转移以及物质的结构、光谱和磁特性的相应变化。详细研究了导致物理性质滞后现象的合作相互作用。提供了具有自旋跃迁的化合物实际应用的前景领域。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Influence of Cooperative Interactions on the Spin Crossover Phenomenon in Iron(II) Complexes: A Review

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Influence of Cooperative Interactions on the Spin Crossover Phenomenon in Iron(II) Complexes: A Review

The theoretical principles of a spin transition phenomenon in pseudo-octahedral iron(II) complexes are summarized. The intrinsic transfer of electrons between d-orbitals of a central ion under the action of external factors and the corresponding changes in the structural, spectral, and magnetic characteristics of matter are considered. Cooperative interactions that lead to the appearance of hysteresis of physical properties have been studied in detail. Perspective areas of practical applications of compounds with spin transitions have been provided.

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来源期刊

Theoretical and Experimental Chemistry CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

1.60

自引率

10.00%

发文量

审稿时长

6-12 weeks

期刊介绍： Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as: a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials; b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions; c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.