EI质谱法测定未知物质结构的方案。二、单环脂环族、杂环族和芳香族化合物中的诊断离子

IF 4.4 2区 工程技术 Q2 CHEMISTRY, MULTIDISCIPLINARY
A. Mikaia
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引用次数: 1

摘要

讨论了含有三个或更多成员的单个环的饱和碳环烃的电子电离(EI)质谱,然后对其不饱和类似物(包括芳烃)进行了检查。考虑了每个环中有一个、两个、三个或更多杂原子的杂环化合物及其单不饱和和多不饱和类似物的质谱特征。(a)周期大小的影响;(b) 环中元素的数量、性质和位置;(c) 环取代基的位置和性质;以及(d)揭示了解离上不饱和度的性质和位置。确定了这些化合物的特征离解方向以及在其光谱中具有诊断意义的离子。建立了EI下脂环族、杂环族和芳香族化合物的基本离解规则,以进一步用于分析含有这些结构元素的复杂化学物质。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Protocol for structure determination of unknowns by EI mass spectrometry. II. Diagnostic ions in one ring alicyclic, heterocyclic, and aromatic compounds
Electron ionization (EI) mass spectra of saturated carbocyclic hydrocarbons containing a single ring with three or more members are discussed followed by the examination of their unsaturated analogs, including aromatic hydrocarbons. Mass spectrometry characteristics of heterocyclic compounds for each cycle size with one, two, three, and more hetero-atoms in a ring are considered along with their mono- and polyunsaturated analogs. An effect of the (a) size of a cycle; (b) number, nature, and location of elements in a ring; (c) position and nature of ring substituents; and (d) nature and location of unsaturation on the dissociation is revealed. Characteristic dissociation directions of these compounds and diagnostically important ions in their spectra are identified. Basic dissociation rules for alicyclic, heterocyclic, and aromatic compounds under EI are established for further use in the analysis of complex chemicals containing these structural elements.
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来源期刊
CiteScore
6.90
自引率
11.60%
发文量
14
审稿时长
>12 weeks
期刊介绍: The Journal of Physical and Chemical Reference Data (JPCRD) is published by AIP Publishing for the U.S. Department of Commerce National Institute of Standards and Technology (NIST). The journal provides critically evaluated physical and chemical property data, fully documented as to the original sources and the criteria used for evaluation, preferably with uncertainty analysis. Critical reviews may also be included if they document a reference database, review the data situation in a field, review reference-quality measurement techniques, or review data evaluation methods.
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