{"title":"不同金属氧化物对PbO-CdO-SiO2-B2O3-Al2O3体系玻璃理化性质的影响","authors":"N. S. Lozinskii, Ya. A. Moroz, A. N. Lopanov","doi":"10.1134/S1087659622601101","DOIUrl":null,"url":null,"abstract":"<p>The physicochemical processes occurring in glasses of the PbO–CdO–SiO<sub>2</sub>–B<sub>2</sub>O<sub>3</sub>–Al<sub>2</sub>O<sub>3</sub> system after high-temperature contact with oxides of various metals—CuO, NiO, Al<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub>, Nb<sub>2</sub>O<sub>5</sub>, and WO<sub>3</sub>, as well as the electrical resistance of the obtained glasses—are studied by X-ray phase analysis, infrared spectroscopy, and electron paramagnetic resonance. It is established that these properties are determined by the acid-base and redox properties of the oxides and glasses, which directly depend on the content of the O<sup>2–</sup> ion in each specific composition.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":null,"pages":null},"PeriodicalIF":0.8000,"publicationDate":"2023-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of Oxides of Various Metals on the Physicochemical Properties of Glass in the PbO–CdO–SiO2–B2O3–Al2O3 System\",\"authors\":\"N. S. Lozinskii, Ya. A. Moroz, A. N. Lopanov\",\"doi\":\"10.1134/S1087659622601101\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The physicochemical processes occurring in glasses of the PbO–CdO–SiO<sub>2</sub>–B<sub>2</sub>O<sub>3</sub>–Al<sub>2</sub>O<sub>3</sub> system after high-temperature contact with oxides of various metals—CuO, NiO, Al<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub>, Nb<sub>2</sub>O<sub>5</sub>, and WO<sub>3</sub>, as well as the electrical resistance of the obtained glasses—are studied by X-ray phase analysis, infrared spectroscopy, and electron paramagnetic resonance. It is established that these properties are determined by the acid-base and redox properties of the oxides and glasses, which directly depend on the content of the O<sup>2–</sup> ion in each specific composition.</p>\",\"PeriodicalId\":580,\"journal\":{\"name\":\"Glass Physics and Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2023-05-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Glass Physics and Chemistry\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1087659622601101\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Glass Physics and Chemistry","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S1087659622601101","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Effect of Oxides of Various Metals on the Physicochemical Properties of Glass in the PbO–CdO–SiO2–B2O3–Al2O3 System
The physicochemical processes occurring in glasses of the PbO–CdO–SiO2–B2O3–Al2O3 system after high-temperature contact with oxides of various metals—CuO, NiO, Al2O3, TiO2, Nb2O5, and WO3, as well as the electrical resistance of the obtained glasses—are studied by X-ray phase analysis, infrared spectroscopy, and electron paramagnetic resonance. It is established that these properties are determined by the acid-base and redox properties of the oxides and glasses, which directly depend on the content of the O2– ion in each specific composition.
期刊介绍:
Glass Physics and Chemistry presents results of research on the inorganic and physical chemistry of glass, ceramics, nanoparticles, nanocomposites, and high-temperature oxides and coatings. The journal welcomes manuscripts from all countries in the English or Russian language.