新型超级电容器用高性能电极材料SrO0.5:MnO0.5双金属氧化物纳米结构的简易合成

IF 3.1 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
V. Adimule, V. Bhat, B. Yallur, Adarsha HJ Gowda, P. Padova, G. Hegde, A. Toghan
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引用次数: 8

摘要

钙钛矿双金属氧化物作为电极材料的共混物可以是提高超级电容器性能的合适方法。在本研究中,通过简单的共沉淀方法合成了SrO0.5:MnO0.5纳米结构(NS),并在750–800°C下煅烧。通过X射线衍射、表面化学成分和化学键分析对SrO0.5:MnO0.5NS的晶体结构进行了表征,并通过X射线光电子能谱研究证实了SrO在MnO中的分散。通过扫描电子显微镜分析结构形态。使用紫外-可见分光光度计研究了SrO0.5:MnO0.5NS的光学性质,SrO0.5和MnO0.5NS显示出~75nm的晶粒和-64nm的晶界距离,吸收图案强度分别为261nm和345nm处的两个最大值。合成的SrO0.5:MnO0.5NS在0.1A/g的电流密度下表现出392.8F/g的高比电容。电化学阻抗谱结果表明,在1000次恒电流充放电(GCD)循环后,保持了0.2 s~73%的低电阻和非常低的时间常数。这些发现表明,SrO0.5:MnO0.5双金属氧化物材料可能是一种很有前途的电化学储能系统电极材料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Facile synthesis of novel SrO 0.5:MnO 0.5 bimetallic oxide nanostructure as a high-performance electrode material for supercapacitors
Perovskite bimetallic oxides as electrode material blends can be an appropriate method to enhance the supercapacitor properties. In the present research, SrO 0.5:MnO 0.5 nanostructures (NS) were synthesized by a facile co-precipitation method and calcinated at 750–800°C. Crystal structure of SrO 0.5:MnO 0.5 NS were characterized by X-ray diffraction, surface chemical composition and chemical bond analysis, and dispersion of SrO into MnO was confirmed by X-ray photoelectron spectral studies. Structural morphology was analyzed from scanning electron microscopy. Optical properties of SrO 0.5:MnO 0.5 NS were studied using UV-Visible spectrophotometer and SrO 0.5 and MnO 0.5 NS showed ∼75 nm grain, ∼ 64 nm grain boundary distance, with two maxima at 261 nm and 345 nm as intensity of absorption patterns, respectively. The synthesized SrO 0.5:MnO 0.5 NS exhibited high specific capacitance of 392.8 F/g at a current density of 0.1 A/g. Electrochemical impedance spectroscopy results indicated low resistance and very low time constant of 0.2 s ∼73% of the capacitance was retained after 1000 galvanostatic charge-discharge (GCD) cycles. These findings indicate that SrO 0.5:MnO 0.5 bimetallic oxide material could be a promising electrode material for electrochemical energy storage systems.
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来源期刊
Nanomaterials and Nanotechnology
Nanomaterials and Nanotechnology NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
7.20
自引率
21.60%
发文量
13
审稿时长
15 weeks
期刊介绍: Nanomaterials and Nanotechnology is a JCR ranked, peer-reviewed open access journal addressed to a cross-disciplinary readership including scientists, researchers and professionals in both academia and industry with an interest in nanoscience and nanotechnology. The scope comprises (but is not limited to) the fundamental aspects and applications of nanoscience and nanotechnology
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