制备气相色谱分离后溴代碘甲烷的绝对构型

B. Spenger, Stefan Näf, S. Manov, J. Stohner
{"title":"制备气相色谱分离后溴代碘甲烷的绝对构型","authors":"B. Spenger, Stefan Näf, S. Manov, J. Stohner","doi":"10.33774/chemrxiv-2021-51rbh","DOIUrl":null,"url":null,"abstract":"The enantiomers of bromofluoroiodomethane (CHBrFI) were separated on a preparative scale using gas chromatography (GC). The collected single enantiomers were analysed by vibrational circular dichroism spectroscopy and polarimetry in combination with ab initio calculations to determine the respective absolute configuration.","PeriodicalId":72565,"journal":{"name":"ChemRxiv : the preprint server for chemistry","volume":" ","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2021-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Absolute Configuration of Bromofluoroiodomethane after Preparative Gas Chromatographic Separation\",\"authors\":\"B. Spenger, Stefan Näf, S. Manov, J. Stohner\",\"doi\":\"10.33774/chemrxiv-2021-51rbh\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The enantiomers of bromofluoroiodomethane (CHBrFI) were separated on a preparative scale using gas chromatography (GC). The collected single enantiomers were analysed by vibrational circular dichroism spectroscopy and polarimetry in combination with ab initio calculations to determine the respective absolute configuration.\",\"PeriodicalId\":72565,\"journal\":{\"name\":\"ChemRxiv : the preprint server for chemistry\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemRxiv : the preprint server for chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.33774/chemrxiv-2021-51rbh\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemRxiv : the preprint server for chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.33774/chemrxiv-2021-51rbh","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

使用气相色谱法(GC)在制备规模上分离溴代氟碘甲烷(CHBrFI)的对映体。通过振动圆二色光谱法和旋光法结合从头计算对收集的单个对映体进行分析,以确定各自的绝对构型。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Absolute Configuration of Bromofluoroiodomethane after Preparative Gas Chromatographic Separation
The enantiomers of bromofluoroiodomethane (CHBrFI) were separated on a preparative scale using gas chromatography (GC). The collected single enantiomers were analysed by vibrational circular dichroism spectroscopy and polarimetry in combination with ab initio calculations to determine the respective absolute configuration.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信