{"title":"二苯基氧化碲铜(II)/锰(III)配合物[CuII(Ph2TeO)4]Cl2·14H2O和[MnIIICl(Ph2TeO)4]Cl2·4H2O的合成与结构","authors":"Qian-Ya Xu, Yu-Jie Cui, Feng Hu, Ai-Quan Jia, Qian-Feng Zhang","doi":"10.1007/s10870-022-00942-4","DOIUrl":null,"url":null,"abstract":"<div><p>Treatment of diphenyl tellurium oxide (Ph<sub>2</sub>TeO) with CuCl<sub>2</sub>·2H<sub>2</sub>O in a 4:1 molar ratio afforded the copper(II) complex [Cu<sup>II</sup>(Ph<sub>2</sub>TeO)<sub>4</sub>]Cl<sub>2</sub>·14H<sub>2</sub>O (<b>1</b>), in which the copper(II) center is four-coordinated by four oxygen atoms from four Ph<sub>2</sub>TeO units. Reaction of MnCl<sub>2</sub>·4H<sub>2</sub>O, (<sup><i>n</i></sup>Bu<sub>4</sub>N)[MnO<sub>4</sub>] and Ph<sub>2</sub>TeO at a molar ratio of 4:1:16 gave the manganese(III) complex [Mn<sup>III</sup>Cl(Ph<sub>2</sub>TeO)<sub>4</sub>]Cl<sub>2</sub>·4H<sub>2</sub>O (<b>2</b>), in which the manganese(III) center is five-coordinated by one chlorine atom and four oxygen atoms from four Ph<sub>2</sub>TeO moieties. Complex <b>1</b> crystallizes in the triclinic space group <i>P</i>ī, with <i>a</i> = 8.9904(18), <i>b</i> = 13.068(3), <i>c</i> = 13.573(3) Å, <i>α</i> = 100.42(3)°, <i>β</i> = 109.17(3)°, <i>γ</i> = 99.56(3)°, and <i>Z</i> = 1. The unit cell of <b>2</b> has a monoclinic <i>P</i>2<sub>1</sub><i>/c</i> symmetry with the cell parameters <i>a</i> = 20.179(5), <i>b</i> = 13.917(3), <i>c</i> = 19.210(4) Å, <i>β</i> = 94.840(7)°, and <i>Z</i> = 4.</p><h3>Graphical Abstract</h3><p>Two new transition metal complexes with diphenyl tellurium oxide as ligands have been synthesized and studied.</p>\n <figure><div><div><div><picture><source><img></source></picture></div></div></div></figure>\n </div>","PeriodicalId":615,"journal":{"name":"Journal of Chemical Crystallography","volume":"53 1","pages":"1 - 7"},"PeriodicalIF":0.4000,"publicationDate":"2022-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Syntheses and Structures of Diphenyl-Tellurium Oxide Copper(II)/Manganese(III) Complexes [CuII(Ph2TeO)4]Cl2·14H2O and [MnIIICl(Ph2TeO)4]Cl2·4H2O\",\"authors\":\"Qian-Ya Xu, Yu-Jie Cui, Feng Hu, Ai-Quan Jia, Qian-Feng Zhang\",\"doi\":\"10.1007/s10870-022-00942-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Treatment of diphenyl tellurium oxide (Ph<sub>2</sub>TeO) with CuCl<sub>2</sub>·2H<sub>2</sub>O in a 4:1 molar ratio afforded the copper(II) complex [Cu<sup>II</sup>(Ph<sub>2</sub>TeO)<sub>4</sub>]Cl<sub>2</sub>·14H<sub>2</sub>O (<b>1</b>), in which the copper(II) center is four-coordinated by four oxygen atoms from four Ph<sub>2</sub>TeO units. Reaction of MnCl<sub>2</sub>·4H<sub>2</sub>O, (<sup><i>n</i></sup>Bu<sub>4</sub>N)[MnO<sub>4</sub>] and Ph<sub>2</sub>TeO at a molar ratio of 4:1:16 gave the manganese(III) complex [Mn<sup>III</sup>Cl(Ph<sub>2</sub>TeO)<sub>4</sub>]Cl<sub>2</sub>·4H<sub>2</sub>O (<b>2</b>), in which the manganese(III) center is five-coordinated by one chlorine atom and four oxygen atoms from four Ph<sub>2</sub>TeO moieties. Complex <b>1</b> crystallizes in the triclinic space group <i>P</i>ī, with <i>a</i> = 8.9904(18), <i>b</i> = 13.068(3), <i>c</i> = 13.573(3) Å, <i>α</i> = 100.42(3)°, <i>β</i> = 109.17(3)°, <i>γ</i> = 99.56(3)°, and <i>Z</i> = 1. The unit cell of <b>2</b> has a monoclinic <i>P</i>2<sub>1</sub><i>/c</i> symmetry with the cell parameters <i>a</i> = 20.179(5), <i>b</i> = 13.917(3), <i>c</i> = 19.210(4) Å, <i>β</i> = 94.840(7)°, and <i>Z</i> = 4.</p><h3>Graphical Abstract</h3><p>Two new transition metal complexes with diphenyl tellurium oxide as ligands have been synthesized and studied.</p>\\n <figure><div><div><div><picture><source><img></source></picture></div></div></div></figure>\\n </div>\",\"PeriodicalId\":615,\"journal\":{\"name\":\"Journal of Chemical Crystallography\",\"volume\":\"53 1\",\"pages\":\"1 - 7\"},\"PeriodicalIF\":0.4000,\"publicationDate\":\"2022-04-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Chemical Crystallography\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10870-022-00942-4\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CRYSTALLOGRAPHY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical Crystallography","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10870-022-00942-4","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
引用次数: 0
摘要
用CuCl2·2H2O以4:1的摩尔比处理二苯基氧化碲(Ph2TeO)，得到铜(II)配合物[CuII(Ph2TeO)4]Cl2·14H2O(1)，其中铜(II)中心由四个Ph2TeO单元的四个氧原子四配位。MnCl2·4H2O， (nBu4N)[MnO4]和Ph2TeO以4:1:16的摩尔比反应得到锰(III)配合物[MnIIICl(Ph2TeO)4]Cl2·4H2O(2)，其中锰(III)中心由四个Ph2TeO基团的一个氯原子和四个氧原子五配位。复杂1三斜晶系的结晶的空间群Pī= 8.9904 (18),b = 13.068 (3), c = 13.573(3),α= 100.42(3)°,β= 109.17(3)°,γ= 99.56(3)°,Z = 1。2的胞元具有单斜P21/c对称，胞元参数a = 20.179(5)， b = 13.917(3)， c = 19.210(4) Å， β = 94.840(7)°，Z = 4。摘要合成并研究了两种新的以氧化二苯碲为配体的过渡金属配合物。
Syntheses and Structures of Diphenyl-Tellurium Oxide Copper(II)/Manganese(III) Complexes [CuII(Ph2TeO)4]Cl2·14H2O and [MnIIICl(Ph2TeO)4]Cl2·4H2O
Treatment of diphenyl tellurium oxide (Ph2TeO) with CuCl2·2H2O in a 4:1 molar ratio afforded the copper(II) complex [CuII(Ph2TeO)4]Cl2·14H2O (1), in which the copper(II) center is four-coordinated by four oxygen atoms from four Ph2TeO units. Reaction of MnCl2·4H2O, (nBu4N)[MnO4] and Ph2TeO at a molar ratio of 4:1:16 gave the manganese(III) complex [MnIIICl(Ph2TeO)4]Cl2·4H2O (2), in which the manganese(III) center is five-coordinated by one chlorine atom and four oxygen atoms from four Ph2TeO moieties. Complex 1 crystallizes in the triclinic space group Pī, with a = 8.9904(18), b = 13.068(3), c = 13.573(3) Å, α = 100.42(3)°, β = 109.17(3)°, γ = 99.56(3)°, and Z = 1. The unit cell of 2 has a monoclinic P21/c symmetry with the cell parameters a = 20.179(5), b = 13.917(3), c = 19.210(4) Å, β = 94.840(7)°, and Z = 4.
Graphical Abstract
Two new transition metal complexes with diphenyl tellurium oxide as ligands have been synthesized and studied.
期刊介绍：
Journal of Chemical Crystallography is an international and interdisciplinary publication dedicated to the rapid dissemination of research results in the general areas of crystallography and spectroscopy. Timely research reports detail topics in crystal chemistry and physics and their relation to problems of molecular structure; structural studies of solids, liquids, gases, and solutions involving spectroscopic, spectrometric, X-ray, and electron and neutron diffraction; and theoretical studies.
![Syntheses and Structures of Diphenyl-Tellurium Oxide Copper(II)/Manganese(III) Complexes [CuII(Ph2TeO)4]Cl2·14H2O and [MnIIICl(Ph2TeO)4]Cl2·4H2O](https://img.booksci.cn/booksciimg/2022-4/1954917971697573591.jpg)
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