紫外光照射下Gd掺杂Bi2O3对选择性染料的光催化降解

Pub Date : 2022-07-01 DOI:10.15251/jobm.2022.143.77
E. Dhanasekaran, N. Sivakumar, N. Sriharan
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引用次数: 0

摘要

采用简单水热法合成了纳米棒状结构裸Bi2O3和gd掺杂Bi2O3 (Gd-Bi2O3)。采用x射线粉末衍射(XRD)、扫描电子显微镜(SEM)、x射线能谱(EDS)和紫外可见吸收光谱(UV)对合成的纳米颗粒的晶体结构、组成和表面形貌进行了表征。通过在pH = 4、6、8的紫外光作用下对不同类别染料水溶液的降解,评价了合成样品的光催化效率。与裸Bi2O3相比,Gd-Bi2O3对染料有明显的降解作用。本文简要介绍了影响Gd-Bi2O3光催化活性的主要因素及可能的光催化降解机理。
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Enhanced photocatalytic degradation of Gd-doped Bi2O3 for selective dyes under UV light irradiation
Nanorod like structured bare Bi2O3 and Gd-doped Bi2O3 (Gd-Bi2O3) are synthesized by simple hydrothermal method. The crystal structure, compositions and surface morphology of the synthesized nanoparticles are characterized by X-ray powder diffraction (XRD), Scanning electron microscopy (SEM), Energy Dispersive X-ray spectroscopy (EDS) and UV-visible absorbance spectroscopy (UV). The photocatalytic efficiency of as synthesized samples is evaluated by degradation of aqueous solution of dyes from different classes under the pH = 4, 6, 8 in presence of UV light. Comparatively, Gd-Bi2O3 exhibits significant degradation of dye stuffs than bare Bi2O3. In our present study, the factors which are emphasis the photocatalytic activity of Gd-Bi2O3 and possible mechanism for photocatalytic degradation also narrated briefly.
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