棕榈酸、油酸钙与乙酰胺、烟酰胺和硫代酰胺的混合配合物

Q4 Materials Science
А. I. Тursunoy, A. A. Tokhir, R. I. Мavluda
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引用次数: 0

摘要

合成了棕榈酸酯和油酸钙的混合配位化合物。建立了棕榈酸酯和油酸酯片段、乙酰胺、烟酰胺和硫代氨基酰胺分子的组成、个性、热行为、配位方法。对比了棕榈酸钙和油酸钙、游离配体分子和合成物的衍射图,发现了衍射图的不匹配,证明了合成物具有不同于原料的单个晶体。用红外光谱法证明了酰胺分子的配位方法,即中心离子的环境。乙酰胺分子通过一个氧原子与中心原子配位,硫代氨基酰胺和烟酰胺分子分别通过硫原子和氮原子配位,棕榈酸酯和油酸酯片段斜对配位。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
MIXED COMPLEX COMPOUNDS OF PALMITATE, OLEATE CALCIUM WITH ACETAMIDE, NICOTINAMIDE AND THIOCARBAMIDE
The mixed coordination compounds of palmitate and calcium oleate were synthesized. Thecomposition, individuality, thermal behavior, methods of coordinating the palmitate and oleate fragments,acetamide, nicotinamide and thiocarbamide molecules have been established. Comparison of the diffractionpatterns of calcium palmitate and oleate, free ligand molecules and synthesized compounds showed themismatch of the diffractograms, and this proves that the synthesized complexes have an individual crystallattice different from the starting materials. The method of coordination of amide molecules, theenvironment of the central ion, is proved by IR spectroscopy. Acetamide molecules are coordinated with thecentral atom through an oxygen atom, thiocarbamide and nicotinamide molecules are coordinated throughsulfur and nitrogen atoms, respectively, palmitate and oleate fragments coordinate bidentantly.
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来源期刊
Solid State Technology
Solid State Technology 工程技术-工程:电子与电气
CiteScore
0.30
自引率
0.00%
发文量
0
审稿时长
>12 weeks
期刊介绍: Information not localized
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