{"title":"几种土壤系列钾行为测定吸附模型的比较","authors":"Nabeel Rizwan, Q. Khan","doi":"10.21743/pjaec/2021.06.09","DOIUrl":null,"url":null,"abstract":"Potassium (K) availability to plants varies with the adsorption characteristics of soil, to evaluate the adsorption capacity, five soil series of different characteristics were used. K adsorption isotherms were performed by equilibrating 2.5 g soil samples with 10 levels of K (30-300 mg kg-1) as KCl in 0.01 CaCl2 solutions and shaken for 24 h at 25oC. The amount of K adsorbed ranged from 33.2 to 94.9% of added K. Freundlich model explained K adsorption behavior better than the other two equations. Higher coefficient of regression values 0.99, 0.97 and 0.96 were recorded in Sultanpur (Silt loam), Naivela (Fine sandy loam) and Bhutesar (Clay loam), respectively. The highest 1/n value 1.54 kg mg-1 and kf value 31.47 mg kg-1 of Freundlich isotherm were observed in Sultanpur (silt loam) due to high pH, high OM and high clay contents, lowest values of constants were observed in Wajan (loamy sand) with 1/n value 0.44 kg mg-1 and kf value 0.28 mg kg-1 might be due to high EC, high CaCO3 and sand contents. The K adsorption of soil varied with physico – chemical characteristics of soil, especially clay content, alkaline pH and organic matter content.","PeriodicalId":19846,"journal":{"name":"Pakistan Journal of Analytical & Environmental Chemistry","volume":" ","pages":""},"PeriodicalIF":0.4000,"publicationDate":"2021-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Comparison of Adsorption Models for Determining Potassium Behavior in of Some Selected Soil Series\",\"authors\":\"Nabeel Rizwan, Q. Khan\",\"doi\":\"10.21743/pjaec/2021.06.09\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Potassium (K) availability to plants varies with the adsorption characteristics of soil, to evaluate the adsorption capacity, five soil series of different characteristics were used. K adsorption isotherms were performed by equilibrating 2.5 g soil samples with 10 levels of K (30-300 mg kg-1) as KCl in 0.01 CaCl2 solutions and shaken for 24 h at 25oC. The amount of K adsorbed ranged from 33.2 to 94.9% of added K. Freundlich model explained K adsorption behavior better than the other two equations. Higher coefficient of regression values 0.99, 0.97 and 0.96 were recorded in Sultanpur (Silt loam), Naivela (Fine sandy loam) and Bhutesar (Clay loam), respectively. The highest 1/n value 1.54 kg mg-1 and kf value 31.47 mg kg-1 of Freundlich isotherm were observed in Sultanpur (silt loam) due to high pH, high OM and high clay contents, lowest values of constants were observed in Wajan (loamy sand) with 1/n value 0.44 kg mg-1 and kf value 0.28 mg kg-1 might be due to high EC, high CaCO3 and sand contents. The K adsorption of soil varied with physico – chemical characteristics of soil, especially clay content, alkaline pH and organic matter content.\",\"PeriodicalId\":19846,\"journal\":{\"name\":\"Pakistan Journal of Analytical & Environmental Chemistry\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.4000,\"publicationDate\":\"2021-06-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Pakistan Journal of Analytical & Environmental Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.21743/pjaec/2021.06.09\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Pakistan Journal of Analytical & Environmental Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.21743/pjaec/2021.06.09","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0
摘要
植物对钾的有效性随土壤的吸附特性而变化,为了评价植物对钾的吸附能力,采用了5个不同特性的土壤系列。将2.5 g土壤样品与10个水平的K (30-300 mg kg-1)作为KCl在0.01 CaCl2溶液中平衡,并在25℃下振荡24 h,进行K吸附等温线。吸附K的量在加入K的33.2 ~ 94.9%之间,Freundlich模型较好地解释了K的吸附行为。Sultanpur(粉砂壤土)、Naivela(细砂壤土)和Bhutesar(粘土壤土)的回归系数分别为0.99、0.97和0.96。由于高pH、高OM和高粘土含量,Sultanpur(粉质壤土)Freundlich等温线的1/n值最高为1.54 kg mg-1, kf值为31.47 mg kg-1, Wajan(壤土砂)的常数值最低,1/n值为0.44 kg mg-1, kf值为0.28 mg kg-1,这可能是由于高EC、高CaCO3和高砂含量所致。土壤对钾的吸附随土壤理化特性的不同而不同,特别是粘土含量、碱性pH值和有机质含量。
Comparison of Adsorption Models for Determining Potassium Behavior in of Some Selected Soil Series
Potassium (K) availability to plants varies with the adsorption characteristics of soil, to evaluate the adsorption capacity, five soil series of different characteristics were used. K adsorption isotherms were performed by equilibrating 2.5 g soil samples with 10 levels of K (30-300 mg kg-1) as KCl in 0.01 CaCl2 solutions and shaken for 24 h at 25oC. The amount of K adsorbed ranged from 33.2 to 94.9% of added K. Freundlich model explained K adsorption behavior better than the other two equations. Higher coefficient of regression values 0.99, 0.97 and 0.96 were recorded in Sultanpur (Silt loam), Naivela (Fine sandy loam) and Bhutesar (Clay loam), respectively. The highest 1/n value 1.54 kg mg-1 and kf value 31.47 mg kg-1 of Freundlich isotherm were observed in Sultanpur (silt loam) due to high pH, high OM and high clay contents, lowest values of constants were observed in Wajan (loamy sand) with 1/n value 0.44 kg mg-1 and kf value 0.28 mg kg-1 might be due to high EC, high CaCO3 and sand contents. The K adsorption of soil varied with physico – chemical characteristics of soil, especially clay content, alkaline pH and organic matter content.