B. Satpathy, Sambedan Jena, Siddhartha Das, K. Das
{"title":"综合评述了各种用于生产银和金镀层的无氰电镀槽","authors":"B. Satpathy, Sambedan Jena, Siddhartha Das, K. Das","doi":"10.1080/09506608.2022.2156723","DOIUrl":null,"url":null,"abstract":"ABSTRACT Cyanide-based baths are generally used industrially to produce silver and gold coatings via electroplating. Baths containing ([Au(CN)2]−) and ([Ag(CN)2]−) are used for the deposition of gold and silver coatings, respectively. However, due to the severe toxicity, the technical personnel involved in work are at risk. Additionally, the disposal of cyanide-containing wastes poses a significant threat to the environment as they pollute various natural resources. The coatings produced from alkaline cyanide-based baths cause embrittlement of electronic circuit patterns. Due to these reasons, many cyanide-free baths have started to replace the existing cyanide-based baths. In the cyanide-free baths, the primary cyanide complexing agent is replaced with eco-friendly alternative compounds like sulphite, thiosulphate, thiourea, DMH, EDTA, and ionic liquids (ILs). This review article provides an overview of the various cyanide-free electroplating baths available for electroplating silver and gold that are either used for commercial practice or are developed for laboratory-scale use. GRAPHICAL ABSTRACT","PeriodicalId":14427,"journal":{"name":"International Materials Reviews","volume":" ","pages":""},"PeriodicalIF":16.8000,"publicationDate":"2022-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"10","resultStr":"{\"title\":\"A comprehensive review of various non-cyanide electroplating baths for the production of silver and gold coatings\",\"authors\":\"B. Satpathy, Sambedan Jena, Siddhartha Das, K. Das\",\"doi\":\"10.1080/09506608.2022.2156723\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACT Cyanide-based baths are generally used industrially to produce silver and gold coatings via electroplating. Baths containing ([Au(CN)2]−) and ([Ag(CN)2]−) are used for the deposition of gold and silver coatings, respectively. However, due to the severe toxicity, the technical personnel involved in work are at risk. Additionally, the disposal of cyanide-containing wastes poses a significant threat to the environment as they pollute various natural resources. The coatings produced from alkaline cyanide-based baths cause embrittlement of electronic circuit patterns. Due to these reasons, many cyanide-free baths have started to replace the existing cyanide-based baths. In the cyanide-free baths, the primary cyanide complexing agent is replaced with eco-friendly alternative compounds like sulphite, thiosulphate, thiourea, DMH, EDTA, and ionic liquids (ILs). This review article provides an overview of the various cyanide-free electroplating baths available for electroplating silver and gold that are either used for commercial practice or are developed for laboratory-scale use. GRAPHICAL ABSTRACT\",\"PeriodicalId\":14427,\"journal\":{\"name\":\"International Materials Reviews\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":16.8000,\"publicationDate\":\"2022-12-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"10\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Materials Reviews\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1080/09506608.2022.2156723\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Materials Reviews","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1080/09506608.2022.2156723","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
A comprehensive review of various non-cyanide electroplating baths for the production of silver and gold coatings
ABSTRACT Cyanide-based baths are generally used industrially to produce silver and gold coatings via electroplating. Baths containing ([Au(CN)2]−) and ([Ag(CN)2]−) are used for the deposition of gold and silver coatings, respectively. However, due to the severe toxicity, the technical personnel involved in work are at risk. Additionally, the disposal of cyanide-containing wastes poses a significant threat to the environment as they pollute various natural resources. The coatings produced from alkaline cyanide-based baths cause embrittlement of electronic circuit patterns. Due to these reasons, many cyanide-free baths have started to replace the existing cyanide-based baths. In the cyanide-free baths, the primary cyanide complexing agent is replaced with eco-friendly alternative compounds like sulphite, thiosulphate, thiourea, DMH, EDTA, and ionic liquids (ILs). This review article provides an overview of the various cyanide-free electroplating baths available for electroplating silver and gold that are either used for commercial practice or are developed for laboratory-scale use. GRAPHICAL ABSTRACT
期刊介绍:
International Materials Reviews (IMR) is a comprehensive publication that provides in-depth coverage of the current state and advancements in various materials technologies. With contributions from internationally respected experts, IMR offers a thorough analysis of the subject matter. It undergoes rigorous evaluation by committees in the United States and United Kingdom for ensuring the highest quality of content.
Published by Sage on behalf of ASM International and the Institute of Materials, Minerals and Mining (UK), IMR is a valuable resource for professionals in the field. It is available online through Sage's platform, facilitating convenient access to its wealth of information.
Jointly produced by ASM International and the Institute of Materials, Minerals and Mining (UK), IMR focuses on technologies that impact industries dealing with metals, structural ceramics, composite materials, and electronic materials. Its coverage spans from practical applications to theoretical and practical aspects of material extraction, production, fabrication, properties, and behavior.