{"title":"溶胶-凝胶合成和旋涂SiO2/TiO2多层膜的光学研究","authors":"S. Saravanan, R. S. Dubey, P. Subbarao","doi":"10.1680/jnaen.22.00039","DOIUrl":null,"url":null,"abstract":"In this work, SiO2/TiO2 multilayer films were deposited on silicon substrates via sol-gel spin-coating techniques with the precursors of titanium butoxide and tetraethyl orthosilicate. After the preparation studied the various optical and morphological properties by using X-ray diffractometer (XRD), Fourier transform infrared (FTIR) spectroscopy, and UV-Visible spectrometer. XRD patterns revealed the intense diffraction peaks which were found that the anatase-TiO2 and well-matched with the standard JCPDS file. With the intense peaks, calculated the crystallite size of the prepared samples are 24 nm for three stacks (3S)-SiO2/TiO2 and 30 nm for five stacks (5S)-SiO2/TiO2 thin films using Debye Scherrer’s formula.FTIR transmittance spectra were confirmed the Si-O-Ti vibrational modes at 800 and 960 cm−1 with related functional groups. The reflectance of 86% was noticed by UV-Visible spectrophotometer. These dielectric multipliers will be useful in solar cells as the backside reflectors for improved light-harvesting mechanism.","PeriodicalId":44365,"journal":{"name":"Nanomaterials and Energy","volume":" ","pages":""},"PeriodicalIF":0.3000,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Optical investigation of Sol-Gel synthesized and spin-coating SiO2/TiO2 multilayers\",\"authors\":\"S. Saravanan, R. S. Dubey, P. Subbarao\",\"doi\":\"10.1680/jnaen.22.00039\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this work, SiO2/TiO2 multilayer films were deposited on silicon substrates via sol-gel spin-coating techniques with the precursors of titanium butoxide and tetraethyl orthosilicate. After the preparation studied the various optical and morphological properties by using X-ray diffractometer (XRD), Fourier transform infrared (FTIR) spectroscopy, and UV-Visible spectrometer. XRD patterns revealed the intense diffraction peaks which were found that the anatase-TiO2 and well-matched with the standard JCPDS file. With the intense peaks, calculated the crystallite size of the prepared samples are 24 nm for three stacks (3S)-SiO2/TiO2 and 30 nm for five stacks (5S)-SiO2/TiO2 thin films using Debye Scherrer’s formula.FTIR transmittance spectra were confirmed the Si-O-Ti vibrational modes at 800 and 960 cm−1 with related functional groups. The reflectance of 86% was noticed by UV-Visible spectrophotometer. These dielectric multipliers will be useful in solar cells as the backside reflectors for improved light-harvesting mechanism.\",\"PeriodicalId\":44365,\"journal\":{\"name\":\"Nanomaterials and Energy\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.3000,\"publicationDate\":\"2023-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nanomaterials and Energy\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1680/jnaen.22.00039\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nanomaterials and Energy","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1680/jnaen.22.00039","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Optical investigation of Sol-Gel synthesized and spin-coating SiO2/TiO2 multilayers
In this work, SiO2/TiO2 multilayer films were deposited on silicon substrates via sol-gel spin-coating techniques with the precursors of titanium butoxide and tetraethyl orthosilicate. After the preparation studied the various optical and morphological properties by using X-ray diffractometer (XRD), Fourier transform infrared (FTIR) spectroscopy, and UV-Visible spectrometer. XRD patterns revealed the intense diffraction peaks which were found that the anatase-TiO2 and well-matched with the standard JCPDS file. With the intense peaks, calculated the crystallite size of the prepared samples are 24 nm for three stacks (3S)-SiO2/TiO2 and 30 nm for five stacks (5S)-SiO2/TiO2 thin films using Debye Scherrer’s formula.FTIR transmittance spectra were confirmed the Si-O-Ti vibrational modes at 800 and 960 cm−1 with related functional groups. The reflectance of 86% was noticed by UV-Visible spectrophotometer. These dielectric multipliers will be useful in solar cells as the backside reflectors for improved light-harvesting mechanism.