对高铼酸盐晶体化学的贡献：新型CdTh[MoO4]3型化合物的晶体结构

IF 0.9 4区材料科学 Q3 CRYSTALLOGRAPHY

Zeitschrift Fur Kristallographie-Crystalline Materials Pub Date : 2022-10-17 DOI:10.1515/zkri-2022-0043

D. Charkin, P. Chachin, Evgenii V. Nazarchuk, O. Siidra

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引用次数: 0

摘要

摘要利用熔体蒸发和溶液蒸发技术，从高铼酸盐AI[ReO4]和MII[ReO4]2分别制备了四种新的高铼酸盐AIMII[ReO4]3的单晶（AI=Na，MII=Pb；AI=Na、MII=Sr，Ag，K）。所有新化合物都属于六方CdTh[MoO4]3结构类型，类似于先前已知的NaCa[ReO4]3。我们讨论了这种结构类型中的晶体化学关系，并提出了一些涉及其他四面体阴离子的更具代表性的存在。

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A contribution to the perrhenate crystal chemistry: the crystal structures of new CdTh[MoO4]3-type compounds

Abstract Singe crystals of four new AIMII[ReO4]3 perrhenates (AI = Na, MII = Pb; AI = Na, MII = Sr, Ag, K) have been prepared from the respective AI[ReO4] and MII[ReO4]2 perrhenates using melt and solution evaporation techniques. All new compounds belong to the hexagonal CdTh[MoO4]3 structure type, similar to previously known NaCa[ReO4]3. We discuss the crystal chemical relationships within this structure type and suggest existence of some more representatives involving other tetrahedral anions.

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来源期刊

Zeitschrift Fur Kristallographie-Crystalline Materials CRYSTALLOGRAPHY-

CiteScore

2.00

自引率

16.70%

发文量

期刊介绍： Zeitschrift für Kristallographie – Crystalline Materials was founded in 1877 by Paul von Groth and is today one of the world’s oldest scientific journals. It offers a place for researchers to present results of their theoretical experimental crystallographic studies. The journal presents significant results on structures and on properties of organic/inorganic substances with crystalline character, periodically ordered, modulated or quasicrystalline on static and dynamic phenomena applying the various methods of diffraction, spectroscopy and microscopy.