摩擦表面油膜结构粘度变化与富勒烯组成的关系

A. Kravtsov
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引用次数: 0

摘要

在这项工作中,进一步发展了在摩擦系统摩擦表面形成含富勒烯油膜的物理现象,与已知的相比,它考虑了摩擦表面静电场作用下形成的油膜的结构粘度和结构。负载的增加使凝胶结构的结构粘度显著增加13 - 20倍。基础润滑剂中富勒烯的浓度对液体组成和凝胶结构中聚集体的动态粘度没有显著影响。基础润滑剂介质摩擦学性能的增加使凝胶在摩擦表面的结构粘度值降低了3倍。同时,富勒烯浓度在0.5 - 1.5%范围内对这些指标的影响不大。这种现象可以通过在基础润滑介质中存在或不存在添加剂包来解释。对于那些添加剂包不存在或以少量J/m3存在的油,富勒烯组合物的引入促进了簇和胶束的形成,从而增加了结构粘度,从而在摩擦表面以凝胶结构的形式形成薄膜。相反,如果将富勒烯加入到含有大量均衡添加剂的基础油中,其摩擦学性能高J/m3,则不会发生分子水平上的相互作用。富勒烯在较小程度上会以胶束的形式形成稳定的聚集体。减少摩擦系数的效果,等于96%,是典型的低和中等负荷运行的摩擦系统和基础润滑剂具有平均的摩擦学性能。随着基础油载荷或摩擦学性能的增加,富勒烯的使用效果降低。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Dependences of changes in the structural viscosity of oil films on the friction surface with fullerene compositions
In this work, the physical phenomenon of the formation of an oil film containing fullerenes was further developed, on the friction surface of tribosystems, which, in contrast to the known ones, takes into account the structural viscosity and structure of the formed film under the action of the electrostatic field of the friction surface. An increase in load significantly increases the structural viscosity of the gel structure, 13 - 20 times. The concentration of fullerenes in the base lubricant does not significantly affect the dynamic viscosity of aggregates in the composition of the liquid and the structure of the gel. An increase in the tribological properties of the base lubricant medium reduces the value of the structural viscosity of the gel on the friction surface by a factor of 3. At the same time, the concentration of fullerenes in the range of 0.5 - 1.5% does not have a large effect on these indicators. This phenomenon can be explained by the presence or absence of an additive package in the base lubricating medium. For those oils where the additive package is absent or present in a small amount J/m3, the introduction of a fullerene composition promotes the formation of clusters and micelles, which increase the structural viscosity and, consequently, form a film on the friction surface in the form of a gel structure. Conversely, if fullerenes are introduced into a base oil that contains a large and balanced additive package, where tribological properties are high J/m3, interaction at the molecular level does not occur. Fullerenes to a lesser extent will form stable aggregates in the form of micelles. The effect of reducing the coefficient of friction, equal to 96 %, is typical for low and medium loads of operation of tribosystems and base lubricants with average values of tribological properties. With increasing loads or tribological properties of base oils, the effect of the use of fullerenes decreases.
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