重Xe22+离子相互作用过程中辐射损伤积累对氧化锆陶瓷热物性参数变化的影响研究

Q3 Engineering
A.L. A.L. Kozlovskiy
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引用次数: 0

摘要

本文的目的是评价在230 MeV重离子Xe22+的辐照下,氧化锆陶瓷近表层以点缺陷、位错、空位等形式的辐射损伤形成过程及其积累和局部无序区形成过程对陶瓷热物理性能变化的影响。选择辐照离子类型是由于有可能模拟与核燃料核反应中铀原子核裂变碎片的影响相当的辐射损伤过程。选择zro2陶瓷作为辐照材料,主要是考虑到其作为新一代反应堆分散核燃料惰性基质的主要材料的前景。这种选择是由于zro2陶瓷的物理化学,热物理和强度特性,它比其他类型的氧化物陶瓷更耐腐蚀。在研究过程中发现,在低辐照影响下形成孤立的局部非均质区不会导致受损陶瓷层的热物理性质发生显著变化。然而,t-ZrO2→c- zro2型的多晶转变发生在1012离子/cm2以上的辐照影响下,导致热导率下降,并出现与受损层中声子传热机制破坏相关的热损失。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Study of the influence of radiation-induced damage accumulation during the interaction of heavy Xe22+ ions on changes in the thermophysical parameters of zirconia ceramics
The aim of this paper is to evaluate the influence of the processes of radiation-induced damage formation in the form of point defects, dislocations and vacancies, as well as their accumulation and the formation of locally disorderedregions in the near-surface layer of zirconia ceramics under irradiation with heavy Xe22+ions with an energy of 230 MeV, on the change in the thermophysical properties of ceramics. The choice of the ion type for irradiation is due to the possibilities ofmodeling radiation damage processes comparable to the impact of uranium nuclei fission fragments during nuclear reactions in nuclear fuel. The choice of materials for irradiation in the form of ZrO2ceramics is due to the prospects for their use as the main material for inert matrices of dispersed nuclear fuel for new generation reactors. This choice is due to the physicochemical, thermophysical and strength properties of ZrO2ceramics, which are more resistant than other types of oxide ceramics. During research, it was found that the formation of isolated locally heterogeneous regions at low irradiation fluences does not lead to significant changes in the thermophysical properties of the damaged ceramic layer. However, polymorphic transformations of the t-ZrO2 → c-ZrO2type, which occur at irradiation fluences above 1012ion/cm2, lead to a decrease in thermal conductivity and the appearance of heat losses associated with the disruption of the phonon heat transfer mechanisms in the damaged layer.
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CiteScore
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