Na2Cu+[Cu2+ 30o](AsO4)2Cl和Cu3[cu30o]2(PO4)4Cl2:基于氧中心四面体链的两种新结构类型

IF 0.9 4区 材料科学 Q3 CRYSTALLOGRAPHY
I. V. Kornyakov, S. Krivovichev
{"title":"Na2Cu+[Cu2+ 30o](AsO4)2Cl和Cu3[cu30o]2(PO4)4Cl2:基于氧中心四面体链的两种新结构类型","authors":"I. V. Kornyakov, S. Krivovichev","doi":"10.1515/zkri-2022-0046","DOIUrl":null,"url":null,"abstract":"Abstract Single crystals of Na2Cu+[Cu2+3O](AsO4)2Cl (1) and Cu3[Cu3O]2(PO4)4Cl2 (2) were prepared by chemical vapor transport reactions. Both crystal structures are based upon the same [O2Cu6]8+ chains formed by corner-sharing (OCu4)6+ tetrahedra and interconnected by (TO4)3− (T = P, As) tetrahedra into porous {[OCu3](TO4)2Cl}3− frameworks. The channels within the frameworks are occupied by Na+, Cu+ and Cl− ions in the crystal structure of 1, whereas the channels in the structure of 2 contain edge-sharing CuO4Cl tetragonal pyramids. Both compounds are structurally related to the previously described synthetic Na2Cu+[Cu2+3O](PO4)2Cl and NaCu2+[Cu2+3O](PO4)2Cl. The compound 2 is structurally and chemically related to yaroshevskite, Cu3[Cu3O]2(VO4)4Cl2, a mineral discovered in volcanic fumaroles, but the two structure types are drastically different. The crystal chemical analysis of the title and related compounds allows to recognize a family of at least four compounds based upon {[OCu3](TO4)2Cl}3− frameworks with channels occupied by different chemical constituents.","PeriodicalId":48676,"journal":{"name":"Zeitschrift Fur Kristallographie-Crystalline Materials","volume":"237 1","pages":"343 - 350"},"PeriodicalIF":0.9000,"publicationDate":"2022-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Na2Cu+[Cu2+3O](AsO4)2Cl and Cu3[Cu3O]2(PO4)4Cl2: two new structure types based upon chains of oxocentered tetrahedra\",\"authors\":\"I. V. Kornyakov, S. Krivovichev\",\"doi\":\"10.1515/zkri-2022-0046\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract Single crystals of Na2Cu+[Cu2+3O](AsO4)2Cl (1) and Cu3[Cu3O]2(PO4)4Cl2 (2) were prepared by chemical vapor transport reactions. Both crystal structures are based upon the same [O2Cu6]8+ chains formed by corner-sharing (OCu4)6+ tetrahedra and interconnected by (TO4)3− (T = P, As) tetrahedra into porous {[OCu3](TO4)2Cl}3− frameworks. The channels within the frameworks are occupied by Na+, Cu+ and Cl− ions in the crystal structure of 1, whereas the channels in the structure of 2 contain edge-sharing CuO4Cl tetragonal pyramids. Both compounds are structurally related to the previously described synthetic Na2Cu+[Cu2+3O](PO4)2Cl and NaCu2+[Cu2+3O](PO4)2Cl. The compound 2 is structurally and chemically related to yaroshevskite, Cu3[Cu3O]2(VO4)4Cl2, a mineral discovered in volcanic fumaroles, but the two structure types are drastically different. The crystal chemical analysis of the title and related compounds allows to recognize a family of at least four compounds based upon {[OCu3](TO4)2Cl}3− frameworks with channels occupied by different chemical constituents.\",\"PeriodicalId\":48676,\"journal\":{\"name\":\"Zeitschrift Fur Kristallographie-Crystalline Materials\",\"volume\":\"237 1\",\"pages\":\"343 - 350\"},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2022-08-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Zeitschrift Fur Kristallographie-Crystalline Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1515/zkri-2022-0046\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CRYSTALLOGRAPHY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift Fur Kristallographie-Crystalline Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1515/zkri-2022-0046","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
引用次数: 1

摘要

摘要采用化学气相传递反应制备了Na2Cu+[Cu2+ 30o](AsO4)2Cl(1)和Cu3[cu30o]2(PO4)4Cl2(2)单晶。这两种晶体结构都是基于相同的[O2Cu6]8+链,由共享角(OCu4)6+四面体形成,并由(TO4)3−(T = P, As)四面体连接成多孔的{[OCu3](TO4)2Cl}3−框架。在1晶体结构中,框架内的通道由Na+、Cu+和Cl−离子占据,而在2晶体结构中,框架内的通道含有共享边的CuO4Cl四方金字塔。这两种化合物在结构上与前面描述的合成Na2Cu+[Cu2+ 30o](PO4)2Cl和naacu2 +[Cu2+ 30o](PO4)2Cl相关。化合物2在结构和化学上与亚罗什夫钛矿Cu3[cu30]2(VO4)4Cl2相似,这是一种在火山喷气孔中发现的矿物,但两者的结构类型截然不同。对标题和相关化合物的晶体化学分析允许识别基于{[OCu3](TO4)2Cl}3−框架的至少四个化合物家族,其通道被不同的化学成分占据。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Na2Cu+[Cu2+3O](AsO4)2Cl and Cu3[Cu3O]2(PO4)4Cl2: two new structure types based upon chains of oxocentered tetrahedra
Abstract Single crystals of Na2Cu+[Cu2+3O](AsO4)2Cl (1) and Cu3[Cu3O]2(PO4)4Cl2 (2) were prepared by chemical vapor transport reactions. Both crystal structures are based upon the same [O2Cu6]8+ chains formed by corner-sharing (OCu4)6+ tetrahedra and interconnected by (TO4)3− (T = P, As) tetrahedra into porous {[OCu3](TO4)2Cl}3− frameworks. The channels within the frameworks are occupied by Na+, Cu+ and Cl− ions in the crystal structure of 1, whereas the channels in the structure of 2 contain edge-sharing CuO4Cl tetragonal pyramids. Both compounds are structurally related to the previously described synthetic Na2Cu+[Cu2+3O](PO4)2Cl and NaCu2+[Cu2+3O](PO4)2Cl. The compound 2 is structurally and chemically related to yaroshevskite, Cu3[Cu3O]2(VO4)4Cl2, a mineral discovered in volcanic fumaroles, but the two structure types are drastically different. The crystal chemical analysis of the title and related compounds allows to recognize a family of at least four compounds based upon {[OCu3](TO4)2Cl}3− frameworks with channels occupied by different chemical constituents.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
2.00
自引率
16.70%
发文量
55
期刊介绍: Zeitschrift für Kristallographie – Crystalline Materials was founded in 1877 by Paul von Groth and is today one of the world’s oldest scientific journals. It offers a place for researchers to present results of their theoretical experimental crystallographic studies. The journal presents significant results on structures and on properties of organic/inorganic substances with crystalline character, periodically ordered, modulated or quasicrystalline on static and dynamic phenomena applying the various methods of diffraction, spectroscopy and microscopy.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信