Jonathan R. Valdéz-Camacho, José Domingo Rivera-Ramírez, J. Escalante
{"title":"芳基烯醇与对甲醛的烯烃化反应及其机理研究","authors":"Jonathan R. Valdéz-Camacho, José Domingo Rivera-Ramírez, J. Escalante","doi":"10.4236/IJOC.2019.91002","DOIUrl":null,"url":null,"abstract":"A simple, efficient and low-cost methodology for the synthesis of α-aryl-α,β-unsaturated esters using paraformaldehyde as a source of carbon was developed. Factors that control reaction yields such as temperature, concentration and reaction time were evaluated. A mechanism is proposed based on experimental structures of the intermediates.","PeriodicalId":64796,"journal":{"name":"有机化学国际期刊(英文)","volume":" ","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2019-01-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Studies and Mechanism of Olefination Reaction in Aryl-Enolates with Paraformaldehyde\",\"authors\":\"Jonathan R. Valdéz-Camacho, José Domingo Rivera-Ramírez, J. Escalante\",\"doi\":\"10.4236/IJOC.2019.91002\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A simple, efficient and low-cost methodology for the synthesis of α-aryl-α,β-unsaturated esters using paraformaldehyde as a source of carbon was developed. Factors that control reaction yields such as temperature, concentration and reaction time were evaluated. A mechanism is proposed based on experimental structures of the intermediates.\",\"PeriodicalId\":64796,\"journal\":{\"name\":\"有机化学国际期刊(英文)\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2019-01-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"有机化学国际期刊(英文)\",\"FirstCategoryId\":\"1089\",\"ListUrlMain\":\"https://doi.org/10.4236/IJOC.2019.91002\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"有机化学国际期刊(英文)","FirstCategoryId":"1089","ListUrlMain":"https://doi.org/10.4236/IJOC.2019.91002","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Studies and Mechanism of Olefination Reaction in Aryl-Enolates with Paraformaldehyde
A simple, efficient and low-cost methodology for the synthesis of α-aryl-α,β-unsaturated esters using paraformaldehyde as a source of carbon was developed. Factors that control reaction yields such as temperature, concentration and reaction time were evaluated. A mechanism is proposed based on experimental structures of the intermediates.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
