光催化对映选择反应的最新进展

IF 7.1 2区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Topics in Current Chemistry Pub Date : 2022-09-16 DOI:10.1007/s41061-022-00402-9

Renu Verma, Palvi Jindal, Jagdish Prasad, S. L. Kothari, Narendra Pal Lamba, Anshu Dandia, Rama Kanwar Khangarot, Manmohan Singh Chauhan

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引用次数: 4

摘要

通过光催化对映选择性合成是制备光学活性化合物的首选方法之一。本文通过对h键、过渡金属催化、相转移催化(PTC)、手性Lewis酸催化、n -杂环碳烯催化、胺催化等不同的光催化对映选择反应策略进行了阐述和批判性分析，并对离子对进行了探讨。此外，它解释了不同的催化模式与多功能方法的对映选择性光催化反应。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Recent Trends in Photocatalytic Enantioselective Reactions

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Recent Trends in Photocatalytic Enantioselective Reactions

Enantioselective synthesis through photocatalysis is one of the highly preferred approaches towards preparation of optically active compounds. This review elaborates and critically analyzes the different strategies of photocatalytic enantioselective reactions through H-bonding, transition metal catalysis, phase-transfer catalysis (PTC), chiral Lewis acid catalysis, N-heterocyclic carbene catalysis, and amine catalysis, and also explores ion pairs. In addition, it explains the different catalysis modes with multifunctional approaches for enantioselective photocatalytic reactions.

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来源期刊

Topics in Current Chemistry Chemistry-General Chemistry

CiteScore

13.70

自引率

1.20%

发文量

期刊介绍： Topics in Current Chemistry is a journal that presents critical reviews of present and future trends in modern chemical research. It covers all areas of chemical science, including interactions with related disciplines like biology, medicine, physics, and materials science. The articles in this journal are organized into thematic collections, offering a comprehensive perspective on emerging research to non-specialist readers in academia or industry. Each review article focuses on one aspect of the topic and provides a critical survey, placing it in the context of the collection. Selected examples highlight significant developments from the past 5 to 10 years. Instead of providing an exhaustive summary or extensive data, the articles concentrate on methodological thinking. This approach allows non-specialist readers to understand the information fully and presents the potential prospects for future developments.