环境和生物条件下锗的水溶液化学:无机配体

IF 3.1 3区地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS

Applied Geochemistry Pub Date : 2023-08-01 DOI:10.1016/j.apgeochem.2023.105631

Montserrat Filella , Peter M. May

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引用次数: 1

摘要

现有的平衡常数数据的反应锗与无机配体在水溶液中已严格评估。尽管相关文献很少，而且大多相当古老，但我们已经建立了锗在水、多组分介质中与无机配体最重要的相互作用的热力学描述。这些热力学参数将在环境和(生态)毒理学研究中有用。然而，在现有文献的限制下，重大的不确定性是不可避免的。总的来说，热力学建模的意义是深远的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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The aqueous solution chemistry of germanium under conditions of environmental and biological interest: Inorganic ligands

Available equilibrium constant data for reactions of germanium with inorganic ligands in aqueous solution have been critically evaluated. Even though the relevant literature is sparse and mostly rather old, we have established a working thermodynamic description of germanium in aqueous, multicomponent media for its most important interactions with inorganic ligands. These thermodynamic parameters will be useful in environmental and (eco)toxicology studies. However, within the limitations of the presently available literature, significant uncertainties are inescapable. The implications for thermodynamic modelling in general are far-reaching.

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来源期刊

Applied Geochemistry 地学-地球化学与地球物理

CiteScore

6.10

自引率

8.80%

发文量

272

审稿时长

65 days

期刊介绍： Applied Geochemistry is an international journal devoted to publication of original research papers, rapid research communications and selected review papers in geochemistry and urban geochemistry which have some practical application to an aspect of human endeavour, such as the preservation of the environment, health, waste disposal and the search for resources. Papers on applications of inorganic, organic and isotope geochemistry and geochemical processes are therefore welcome provided they meet the main criterion. Spatial and temporal monitoring case studies are only of interest to our international readership if they present new ideas of broad application. Topics covered include: (1) Environmental geochemistry (including natural and anthropogenic aspects, and protection and remediation strategies); (2) Hydrogeochemistry (surface and groundwater); (3) Medical (urban) geochemistry; (4) The search for energy resources (in particular unconventional oil and gas or emerging metal resources); (5) Energy exploitation (in particular geothermal energy and CCS); (6) Upgrading of energy and mineral resources where there is a direct geochemical application; and (7) Waste disposal, including nuclear waste disposal.