生物医学用PVA-Fe2O3-TiO2杂化结构的合成

Pub Date : 2022-04-01 DOI:10.15251/jobm.2022.142.43
H. M. A. Algelal, S. Kareem, K. A. Mohammed, E. J. Khamees, A. S. Abed, A. H. Alkhayatt, R. R. Al-Okbi
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引用次数: 1

摘要

本工作研究了嵌入Fe2O3–PVA复合基体中的TiO2纳米颗粒的结构、形态和光学性能。使用多种技术对样品进行了检查,包括场发射扫描电子显微镜(FESEM)、X射线衍射(XRD)、吸收和透射光谱以及傅里叶变换红外光谱(FTIR)。晶体学信息显示TiO2的存在对PVA-Fe2O3的晶体结构没有影响。制造的复合材料在440–570 nm范围内表现出较强的吸收能力。重要的是,随着TiO2的存在,这些复合材料的最高吸收逐渐转移到较短的波长区域。PVA-Fe2O3是高度透明的,在600-800nm的范围内具有约85%的透射率。在加入2.5重量%的TiO2纳米颗粒后,在相同波长范围内,纳米复合材料的透射率降至75%。进一步添加纳米颗粒将透射率百分比降低到68%。结果表明,随着TiO2比例的增加,带隙变宽。
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Synthesis of PVA-Fe2O3-TiO2 hybrid structure for biomedical application
This work investigates the structure, morphology, and optical properties of TiO2 nanoparticles embedded in a Fe2O3–PVA composite matrix. The samples were examined using a variety of techniques, including field-emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), absorption and transmission spectra, and Fourier transformation infrared (FTIR). Crystallography information revealed the presence of TiO2 doesn’t effect in the crystal structure of PVA-Fe2O3. The manufactured composites demonstration strong absorption in the range of 440–570 nm. It is important that the highest absorption of these composites gradually shifted to the shorter wavelength region with presence of TiO2. PVA-Fe2O3 is highly transparent with transmittance of around 85 % in range 600-800 nm. After addition of 2.5 % by weight of TiO2 nanoparticles, the transmittance of nanocomposite drops to 75% in the same range of wavelength . Further addition of nanoparticles reduced the percentage transmittance to 68%. The results specify that as the TiO2 ratio increases, the band gap be wider.
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