[4,4′-双（4-氟苯基）-6,6′-二甲基-2,2′-联吡啶][双（2-（二苯基膦基）苯基）醚]六氟磷酸银（I）

IF 0.4 Q4 CHEMISTRY, ORGANIC

Molbank Pub Date : 2023-06-22 DOI:10.3390/m1675

Dimitrios Glykos, J. Plakatouras, G. Malandrinos

引用次数: 0

摘要

合成了一种新型发射杂电性银(I)配合物[AgL(POP)][PF6] (L = 4,4 ' -双(4-氟苯基)-6,6 ' -二甲基-2,2 ' -联吡啶，POP=双(2-(二苯基膦)苯基)醚)，并在固态(x射线晶体学)和溶液中进行了表征。该化合物为黄绿色荧光粉(λem = 528 nm)，量子效率中等(在脱氧二氯甲烷中ΦPL = 25%)。

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[4,4′-Bis(4-fluorophenyl)-6,6′-dimethyl-2,2′-bipyridine] [bis (2-(diphenylphosphino) phenyl) ether] Silver(I) Hexafluorophosphate

A new emissive heteroleptic Ag(I) complex formulated as [AgL(POP)][PF6] (L = 4,4′-bis (4-Fluorophenyl)-6,6′-dimethyl-2,2′-bipyridine, POP= bis (2-(diphenylphosphino) phenyl) ether) was synthesized and characterized in both the solid state (X-ray crystallography) and the solution. The compound is a yellow-green phosphor (λem = 528 nm), with moderate quantum efficiency (ΦPL = 25% in deaerated dichloromethane).

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来源期刊

Molbank Chemistry-Physical and Theoretical Chemistry

CiteScore

0.70

自引率

33.30%

发文量

174

审稿时长

11 weeks

期刊介绍： •organic synthesis •biosynthesis •extraction and purification •natural product derivatives •structural elucidation (X-ray crystallography, NMR, etc.)