一个二茂铁取代亚氨基二乙酰胺及其氯仿溶剂化物的超分子组织研究

IF 0.7 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Croatica Chemica Acta Pub Date : 2017-12-29 DOI:10.5562/CCA3270

N. P. Juraj, J. Pennec, B. Perić, S. Kirin

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引用次数: 4

摘要

本文合成了二茂铁(Fc)、乙二胺(eda)和亚氨基二乙酰胺(imda)的酰胺基共轭物Fc-eda-imda(2)。该化合物(2)在固态和溶液中通过各种光谱、晶体学和热分析技术进行了表征。标题化合物2由甲醇或氯仿结晶，分别得到两种不同的结晶形式2a和2b。在它们的x射线单晶结构中，2a和2b显示出相似的二维氢键网络，但在超分子组织上有所不同，即在三维空间上芳香π - π堆叠相互作用。

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A Case Study of Supramolecular Organization: One Ferrocene Substituted Iminodiacetamide and its Chloroform Solvate

This paper describes the synthesis of an amide based conjugate of ferrocene (Fc), ethylenediamine (eda) and iminodiacetamide (imda), Fc-eda-imda (2). The compound (2) is characterized by various spectroscopic, crystallographic and thermoanalytical techniques in solid state and in solution. By crystallization of the title compound 2 from methanol or chloroform, two different crystalline forms 2a and 2b were obtained, respectively. In their X-ray single crystal structures, 2a and 2b reveal similar 2D hydrogen bonding networks, but differ by supramolecular organization, namely aromatic π – π stacking interactions in the third spatial dimension.

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来源期刊

Croatica Chemica Acta 化学-化学综合

CiteScore

0.60

自引率

0.00%

发文量

审稿时长

18 months

期刊介绍： Croatica Chemica Acta (Croat. Chem. Acta, CCA), is an international journal of the Croatian Chemical Society publishing scientific articles of general interest to chemistry.