表面活性剂/凝胶对硼颗粒在液体燃料中分散稳定性的影响

IF 2.5 Q3 CHEMISTRY, PHYSICAL
J. Bullón, Ronald Marquez, Franklin Zambrano, P. Dilipkumar, S. Sonawane, S. Srinath
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引用次数: 0

摘要

金属基纳米填料被用作分散剂,以提高热导率,从而获得最小的燃料需求,从而提取最大的能量。为了实现这一点,必须将金属基纳米填料均匀悬浮在喷气燃料中,以便实现所需的推进特性。然而,由于密度和粘度是具有分散关系的独立参数,金属基纳米填料在喷气燃料中的分散是一个关键挑战。因此,在目前的工作中,我们打算研究JP-10(Exo-Tetra Hydro双环戊二烯)喷气燃料在不同浓度下分散有硼颗粒(BP)的推进特性。目前工作中涉及的挑战是,由于BP缺乏官能团,因此要使分散在更长的时间内保持稳定。与JP-10一起,是一种单组分、高密度的碳氢化合物,在自然界中可以表现出触变特性,因此与BP结合会使其变得困难;因此,需要低聚或添加衍生自低聚物的表面活性剂。因此,在目前的工作中,通过超声波探针将BP与各种表面活性剂(即端羟基聚丁二烯(HTPB)、Triton X-100、Span 80、油酸和十二烷基硫酸钠(SDS))分散在喷气燃料中,然后研究其稳定性。实验研究报告称,在微米大小的硼颗粒(325±25 nm)下,硼的稳定性最长,达54小时,硼含量为0.5 wt.%,HTPB含量为0.3 wt.%。通过超声波探头的作用实现了颗粒的均匀分散。根据热分析,在50至200°C的短温度范围内,观察到总重量损失25%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of Surfactants/Gels on the Stability of Boron Particle Dispersion in Liquid Fuel
Metal-based nanofillers are used as disperssants to enhance thermal conductivity for a minimal fuel requirement to extract maximum energy. To achieve this, metal-based nanofillers must be suspended uniformly into jet fuel so that desired propulsive characteristics can be achieved. However, the dispersion of the metal-based nanofillers into the jet fuel is a critical challenge due to the density and viscosity that are independent parameters with a scattered relation. Hence, in the current work, we intended to investigate the propulsive characteristics of the JP-10 (Exo-Tetra Hydro Dicyclopentadiene) jet fuel dispersed with boron particles (BP) at various concentrations. The challenge involved in the current work was to make dispersion stable for a longer period due to the absence of functional groups entailed to BPs. Alongside JP-10, is a single-component, high-density hydrocarbon that can that can exhibit thixotropic characteristic in nature and hence combining with BP makes it difficult; hence, there is a need for oligomerization or the addition of surfactants that are derived from oligomers. Hence, in the current work, the BPs were dispersed in jet fuel by the ultrasound probe with various surfactants, namely Hydroxyl Terminated Polybutadiene (HTPB), Triton X-100, Span 80, Oleic acid, and Sodium dodecyl sulfate (SDS), followed by an investigation of their stability. The experimental studies reported that the stability of the boron was longest, for 54 h, with 0.5 wt.% boron and 0.3 wt.% HTPB at a micron size of the boron particles (325 ± 25 nm). The uniform dispersion of the particles was achieved by the effect of the ultrasound probe. From the thermal analysis, a total weight loss of 25% was observed within a short range of temperatures, i.e., 50 to 200 °C.
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来源期刊
Colloids and Interfaces
Colloids and Interfaces CHEMISTRY, PHYSICAL-
CiteScore
3.90
自引率
4.20%
发文量
64
审稿时长
10 weeks
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