三级联反应制备的lawsone及其改性分散染料在尼龙和涤纶织物上的染色性能研究

IF 1.5 Q2 MATERIALS SCIENCE, TEXTILES
Nilam C. Patel, D. Desai, P. N. Patel
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引用次数: 0

摘要

目的本文旨在开发一种新的合成分散染料的方法,该方法是在乙酸锌为催化剂的情况下,与劳松进行三级级联反应。所开发的新型支架对尼龙和聚酯纤维具有高效的染色性能。设计/方法/方法本报告证明了一种有效的三级联方案,用于合成由各种多核甲醛、尿素和lawsone衍生的新型分散染料。发现乙酸锌是该反应的有效催化剂。研究了它们在锦纶和涤纶织物上的染色性能。对两种染色织物的耐洗牢度、升华牢度、颜色评定、损耗率测定和固着性能进行了测试。结果表明,醋酸锌是所开发的三级联方案的有效催化剂。制备的新型分散染料对尼龙和聚酯纤维的染色性能有很大影响。它们显示出比lawsone更明亮的色调、更高的亲和力、吸附能力和更优异的着色强度。与聚酯样品相比,在所有染色的尼龙样品中都发现了很好的耗竭百分比值、固着值、色强度(K/s)值、洗涤和升华牢度。这些结果表明,这些分散染料对尼龙和聚酯纤维日益重要的意义是非常有用的。研究局限性/含义本方案合成制备的分子的外消旋混合物。实际含义开发的协议可用于其他各种三级联过程。这些分子也可用于其他织物的染色。社会意义随着制备的分子的商业化,它可能提供目前分散染料的更好替代品。这可能会影响到社会的各个阶层。独创性/价值本报告介绍了一种在尼龙和聚酯纤维上合成具有高效染色性能的改性新型分散染料的新方案。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Study of lawsone and its modified disperse dyes derived by triple cascade reaction: dyeing performance on nylon and polyester fabrics
Purpose This paper aims to develop a novel protocol for the synthesis of disperse dyes derived by a triple cascade reaction with lawsone in presence of Zn acetate as a catalyst. The developed novel scaffolds have efficient dyeing properties on nylon and polyester fibers. Design/methodology/approach This report demonstrates an effectual triple cascade protocol for the synthesis of novel disperse dyes derived from various polynuclear carbaldehyde, urea and lawsone. The Zn acetate was found to be an effective catalyst for this reaction. Their dyeing performance has been studied on nylon and polyester fabrics. The wash fastness, sublimation fastness, color assessment, determination of percentage exhaustion and fixation properties were applied to both the dyed fabrics. Findings The obtained results indicate that the Zn acetate is an efficient catalyst for the developed triple cascade protocol. The prepared novel disperse dye greatly impacted their dyeing properties on nylon and polyester fibers. They have shown brilliant shades, higher affinity, adsorption capacity, superior tinctorial strength than the lawsone. The percentage exhaustion value, fixation value, color strength (K/s) value, washing and sublimation fastness properties have been found very well in all dyed nylon samples compared to polyester samples. These results discloses that these disperses dyes are very useful to the growing importance of nylon and polyester fibers. Research limitations/implications The present protocol synthesizes the racemic mixture of the prepared molecules. Practical implications Developed protocol can be used for various other triple cascade processes. Also these molecules can be used for dyeing of other fabrics. Social implications With the help of commercialization of prepared molecules, it may provide the better alternative of the current disperse dyes. This may affect the various segments of society. Originality/value This report represents a novel protocol for the synthesis of modified novel disperse dyes with an efficient dyeing properties on nylon and polyester fibers.
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来源期刊
Research journal of textile and apparel
Research journal of textile and apparel MATERIALS SCIENCE, TEXTILES-
CiteScore
2.90
自引率
13.30%
发文量
46
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