水杨酸铜的有序-无序(II)再访

IF 0.7 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Croatica Chemica Acta Pub Date : 2018-06-28 DOI:10.5562/cca3362

M. Lutz, Dai, Louiseinfoeu-repo Kroon Batenburg

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引用次数: 1

摘要

我们重新研究了双水杨酸铜(II)， CuSal的晶体结构，这是一种无序层堆积的OD材料。衍射图样由尖锐的布拉格斑点和漫射条纹组成。从布拉格反射中，我们确定了结构的有序部分，它可以用正交晶格或孪生单斜晶格来描述。该结构的主要基序由一维配位聚合物组成，这些配位聚合物通过氢键连接成二维层。层的堆叠是无序的，并且来自于模拟

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Order-Disorder in Diaquobis(salicylato)copper(II) Revisited

We re-investigated the crystal structure of diaquobis(salicylato)copper(II), CuSal, which is an OD material with disordered layer stacking. The diffraction pattern consists of sharp Bragg spots and diffuse streaks. From the Bragg reflections we determined the ordered part of the structure, which can either be described by an orthorhombic or a twinned monoclinic lattice. The main motif of the structure consists of one-dimensional coordination polymers that are connected by hydrogen bonds into two-dimensional layers. The layer stacking is disordered and from simulation

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来源期刊

Croatica Chemica Acta 化学-化学综合

CiteScore

0.60

自引率

0.00%

发文量

审稿时长

18 months

期刊介绍： Croatica Chemica Acta (Croat. Chem. Acta, CCA), is an international journal of the Croatian Chemical Society publishing scientific articles of general interest to chemistry.